摘要
合成了苯并 18 冠 6(B18C6)与M2 [Pt(SCN)6 ](M =Na,K)的配合物:｛[Na(B18C6)]6 [Pt(SCN)6 ]｝[Pt(SCN)6 ](SCN)2(1),[K(B18C6)]2 [Pt(SCN)6 ]·4H2 O(2).通过元素分析、红外光谱、单晶X射线衍射进行了表征.1为单斜晶系、空间群R3- ,a =b =1 9933(3)nm,c =2 9760 (6)nm,α =β =90°,γ =12 0°,V =10 2 40 (3)nm3,Z =3,Dcalcd=1 5 64g/cm3,F(0 0 0) =490 8,R1=0 0 5 35,wR2 =0 10 30.2为三斜晶系、空间群P1- ,a =1 1692 (3)nm,b =1 185 3(4)nm,c =1 2 381(5)nm,α =61 419(5)°,β =80 75 7(8)°,γ =89 0 0 3(5)°,V =1 4836(9)nm3,Z =1,Dcalcd=1 476g/cm3,F(0 0 0) =666,R1=0 0 696,wR2 =0 134 6. 1由 ｛[Na(B18C6)]6 [Pt(SCN)6 ]｝4 +配阳离子、[Pt(SCN)6 ]2 -配阴离子和SCN-阴离子组成.相邻｛[Na(B18C6)]6 [Pt(SCN)6 ]｝4 +通过Na—O键形成三维网状结构.[Pt(SCN)6 ]2 -和SCN-仅起平衡电荷的作用.2由两个[K(B18C6)]+配阳离子和一个[Pt(SCN)6 ]2 -配阴离子组成.相邻[K(B18C6)]2 [Pt(SCN)6
Novel benzo-18-crown-6 (B18C6) complexes: { [Na(B18C6)](6) [Pt(SCN)(6)] [Pt(SCN)(6)] (SCN)(2) (1) and [K(B18C6)](2) [Pt(SCN)(6)] -4H(2)O (2) were synthesized and characterized by elemental analysis, IR spectra and X-ray diffraction analysis. 1 belongs to rhomobohedral, space group R 3 with cell dimensions: a = b = 1. 9933 (3) nm, c = 2.9760(6) nm, a = beta=90degrees, gamma= 120degrees, V= 10.240(3) nm(3), Z = 3, D-calcd = 1.564 g/cm(3), F(000) = 4908, R-1 = 0. 0535, wR(2) = 0. 1030. 2 is triclinic crystal system, space group P1 with cell dimensions: a = 1. 1692 (3) nm, b = 1. 1853 (4) nm, c = 1.2381 (5) nm, a = 61.419 (5)degrees, beta = 80.757 (8)degrees, gamma = 89.003 (5)degrees, V = 1.4836(9) nm(3), Z = 1, D-calcd = 1.476 g/cm(3), F(000) = 666, R-1 = 0.0696, wR(2) = 0.1346. 1 is composed of one ([Na(B18C6) ](6) [Pt(SCN)(6)]}(4+) complex cation, one [Pt(SCN)(6)](2-) complex anion and two SCN- anions. I [Na(B18C6)](6) [ Pt (SCN)(6)]}(4+) complex cations show a three-dimensional network structure bridged by Na-O interactions between the adjacent [Na(B18C6)] units. The function of [Pt(SCN)(6)](2-) Complex anion and two SCN(-)anions are balancing the charge in the crystal. 2 is made up of two [Na (B18C6)](+) complex cations and one [Pt (SCN) (6) ](2-) complex anion. They form one-dimensional chain structure bridged by K-O interactions between the adjacent [K(B18C6)](+) units.
出处
《化学学报》
SCIE
CAS
CSCD
北大核心
2003年第1期110-116,共7页
Acta Chimica Sinica
