摘要
合成了配合物[Cu(C2H8N2)2(H2O)2]2[Fe(CN)6]4H2O,通过元素分析、红外光谱、单晶X射线衍射进行了表征.配合物属单斜晶系,空间群C2/c,晶体学数据:a=0.7947(4)nm,b=0.8998(5)nm,c=1.0954(6)nm,β=91.380(8)°,V=0.7677(7)nm3,Z=1,F(000)=378,R1=0.0399,wR2=0.0937.配合物由两个[Cu(C2H8N2)2(H2O)2]2+阳离子和一个[Fe(CN)6]4-阴离子组成.并由氢键等弱相互作用形成三维空间结构.
The title complex [Cu(C2H8N2)2(H2O)2]2[-Fe(CN)6-]4H2O has been synthesized and characterized by elemental analysis,IR spectrum and X-ray diffraction analysis. The complex belongs to monoclinic,space group 2C/c ,with cell dimensions, a=0.7947(4)nm,b=0.8998(5)nm,c=1.0954(6)nm,β=91.380(8)°,V=0.7677(7)nm^3,Z=1,F(000)=378,R1=0.0399,wR2=0.0937.
出处
《聊城大学学报(自然科学版)》
2006年第1期9-12,共4页
Journal of Liaocheng University:Natural Science Edition
基金
聊城大学科研基金资助
关键词
配合物
合成与结构
氢键
三维网
the complex, synthesis and crystal structure, hydrogen bonds, three-dimensional network