摘要
多金属催化过程是生命体实现新陈代谢的主要方式之一,在自然界广泛存在.多金属催化剂相比于单金属催化剂,具有更加高的反应活性和对映选择性,近年来其设计与应用已经成为有机化学的研究热点之一.综述了近年来不同种类的具有代表性的双金属催化剂的研究进展,包括双杂金属和双核同金属,介绍了双金属催化剂的反应类型、反应机理以及发展现状,提出了今后的研究重点与发展趋势.
Polymetallic catalytic process is the main metabolic way of life, which is widely observed in nature. Compared to the mono-metal catalysts, the designs and applications of polymetallic catalysts with high reactivity and enantioselectivity have been a hot research topic in organic chemistry recently. This review covers the recent research process on representative types of bimetallic catalysts, including hetero-bimetallic catalysts and dinuclear homometal catalysts, their reaction mechanisms and developments. Moreover, potentially development of this area is also discussed.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2013年第4期749-759,共11页
Chinese Journal of Organic Chemistry
基金
国家自然科学基金(Nos.20972095
21172143
21232004)
上海市科学技术委员会(No.09JC1407800)资助项目~~
关键词
不对称催化
多金属
双核同金属催化剂
双杂金属催化剂
asymmetric catalysis
polymetallic
dinuclear homometal catalyst
hetero-bimetallic catalyst
