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铜(Ⅱ)与2-吡啶酸、4,4′-联吡啶配合物的合成、结构和电化学性质(英文) 被引量：6

Synthesis,Crystal Structure and Cyclic Voltametric Property of Cu(Ⅱ) Complex with 4,4'-Bipy and α-Pyridine Carboxylate
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摘要 The complex [Cu(bipy)(pc)(H2O)(ClO4)]·H2O(1)(bipy:4,4'-bipyridine;Hpc:α-pyridine carboxylic acid) has been synthesized and characterized by single crystal X-ray diffraction method and elemental analysis.It crysrallizes in the Monoclinic space group P21/n.The crystal structure reveals that Cu(Ⅱ) centre adopts a pseudo octahedral geometry.Ligand 4,4'-bipyridine as a bridge coordinates to two different Cu(Ⅱ) center to form a onedimensional zigzag chain.One dimensional chains are linked by C-H…O hydrogen bonding interactions to form two-dimensional layer.Layers are connected by O…H-O hydrogen bond to generate three-dimensional structure.The cyclic voltametric behavior of complex 1 is also investigated. The complex [Cu（bipy）（pc）（H2O）（ClO4）]·H2O（1）（bipy：4,4＇-bipyridine;Hpc：α-pyridine carboxylic acid） has been synthesized and characterized by single crystal X-ray diffraction method and elemental analysis.It crysrallizes in the Monoclinic space group P21/n.The crystal structure reveals that Cu（Ⅱ） centre adopts a pseudo octahedral geometry.Ligand 4,4＇-bipyridine as a bridge coordinates to two different Cu（Ⅱ） center to form a onedimensional zigzag chain.One dimensional chains are linked by C-H…O hydrogen bonding interactions to form two-dimensional layer.Layers are connected by O…H-O hydrogen bond to generate three-dimensional structure.The cyclic voltametric behavior of complex 1 is also investigated.
作者 吴刚 王小锋 鲜华 郭学林
机构地区 滁州学院化学和生命科学系 晓庄学院生物化工与化境工程学院
出处 《无机化学学报》 SCIE CAS CSCD 北大核心 2010年第7期1315-1318,共4页 Chinese Journal of Inorganic Chemistry
基金 安徽省高校自然科学基金资助(No.KJ2009B104) 安徽省应用化学重点建设学科基金资助(No.200802187C)
关键词 Cu髤配合物 4 4′-联吡啶 晶体结构 循环伏安 copper（Ⅱ） complex 4 4＇-bipyridine cyclic voltametry
分类号 O614.121 [理学—无机化学]
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参考文献14

  • 1Leininger S,Olenyuk B,Stang P J.Chenu Rev.,2000,100:853-908.
  • 2Westcott A,Fisher J,Harding L P,et al.J Am.Chem.Soc.,2008,130:2950-2951.
  • 3Coronado E,Cal6n-Mascaros J R,Gomez-Garcia C J,et al.Nature,2000,408:447-449.
  • 4Han F S,Higuchi M,Kurth D G.J.Am.Chem.Soc.,2008,130:2073-2081.
  • 5Hagrman D,Hagrman P J,Zubieta J.Angew.Chem.Int.Ed.,1999,38:3165-3168.
  • 6MacGillivray L R,Atwood J L Angew.Chem.Int.Ed.,1999,38:1018-1033.
  • 7Moulton B,Zaworotko M J.Chem.Rev.,2001,101:1629-1658.
  • 8Lu W G,Su C Y,Lu T B,et al.J.Am.Chem.Soc.,2006,128:34-35.
  • 9Qin C,Wang X L,Li Y G,et al.Baton Trans.,2005:2609-2614.
  • 10Zheng Y Q,Ying E R.Polyhedron,2005,24:397-406.

同被引文献40

  • 1Wang Jun,Wu Weiping,Lu Lu,et al. Self-assembly of wa- ter cluster in Cu(U)complexes and magnetic property[J]. Journal o f Molecular Structure,2013,1036 (27): 174 - 179.
  • 2Tong M L, Kitagawa S,Chang H C,et al. Temperature- controlled hydrotherrml synthesis of a 2D ferromaletic coordination bilayered polymer and a novel 3 D network with inorganic Co3(OH)2 ferrimagnetic chains[J].Chem Commun;2004(4):418-419.
  • 3Wang Jun,Lu Lu,Wu Weiping, et al. Synthesis and Crystal Structure of a New Coordination Polymer Constructed From Rigid Tetracarboxylate and N-Donor Ligands [J]. Synth React Inorg M2012,42(9):1217-1221.
  • 4Rosi N L, Eddaoudi M, Kim J, et al. lnfmite Secondary Building Units and Forbidden Catenation in Metal-Or- ganic Frameworks[J].Angew Chem Int Ed,2002,41 (2): 284-287.
  • 5Lam A W H,Wong W T,Gao S,et al.Synthesis,crystal structure,and photophysical and magnetic properties of dimeric and polymeric lanthanide complexes with benzoic acid and its derivatives[J].Eur J Inorg Chem,003,2003 (1):149-163.
  • 6Shi X, Zhu G S,Fang Q R, et al.Novel supramolecular frameworks self-assembled from one-dimensional poly- meric coordination chains [ J ]. Eur J Inorg Chem, 2004, 2004(1):185-191.
  • 7Huang F,Nagvekar D S,Sllebodnick C,et al.A supmmo- lecular triarm star polymer from a homotritopic tris (crown ether)host and a complementary monotopic pa- raquat-terminated polystyrene vip by a supmmolecular coupling method[J].J Am Chem Soc,2005,127(2):484- 485.
  • 8Shivaiah V,Das S K.Inclusion of a Cu2 Ion by a large- cavity crown ether dibenzo-24-crown-8 through supra- molecular interactions [ J]. Inorg Chem, 2005, 44 (21): 7313-7315.
  • 9Oh M,Carpen G B,Swei D A.Supramolecular metal-or- ganometallic coordination networks based on quinonoid complexes[J].Acc Chem Res2004,37(1):1-11.
  • 10Versteegen R M,Van Beek D,Sijbesma R P,et al.Den- drimer-based transient supramolecular networks [J]. J. Am Chem Soc2005,127(40):13862-13868.

引证文献6

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无机化学学报
2010年 第7期

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