摘要
通过对多种有机溶剂的筛选，发现五种溶剂分子能与六硝基六氮杂异伍兹烷（ＨＮＩＷ）生成分子络合物．二甲基亚砜与ＨＮＩＷ生成等摩尔络合物；二氧六环与ＨＮＩＷ生成３∶２络合物；Ｎ，Ｎ－二甲基甲酰胺、γ－丁内酯与ＨＮＩＷ都生成２∶１络合物；六甲基磷酰三胺与ＨＮＩＷ生成３∶１络合物．还提出了某些结构性质．
A variety of organic solvents likely to complex HNIW was screened. As a result, five new complexes of HNIW were discovered. An equimolar complex was formed with dimethylsulfoxide. Dioxane formed a 3:2 complex with HNIW; N, N-Dimethylformamide and γ-butyrolactone formed 2:1 complexs with HNIW, Hexamethylphosphoramide formed a 3:1 complex with HNIW. Some properties useful in the characterization of the complexes are presented.
出处
《北京理工大学学报》
EI
CAS
CSCD
1996年第5期494-497,共4页
Transactions of Beijing Institute of Technology
关键词
分子络合物
HNIW
NMR
FTIR光谱
多晶型
hexanitrohexaazaisowurtzitane(HNIW)
molecular complex
crystal modifications
FTIR spectra
