摘要
为深入研究和开发臭氧氧化结合化学吸收同时脱除多种污染物技术，阐明了石灰石吸收脱除臭氧氧化产物（SOx和NOx）的吸收反应机理，通过气液固平衡理论对石灰石浆液吸收SOx和NOx特性进行了分析研究。理论分析表明：烟气中CO2对SOx和NOx吸收的影响可以忽略，并给出浆液在吸收容量所能承受的最大气液比。当[CaCO3]=0．05mol／1时，临界点M=600-700；当[CaCO3]=0．1mol／1时，临界点M=1200～1300；当[CaCO3]=0．15mol／1时，临界点M=1900～2000。
The reaction mechanisms of ozone with many pollutants are being elucidated, and the dynamic processes of ozone, oxidizing NOx and SO2 , simulated. According to thermodynamic principles, the partial pressures of SOx and NOx , after the flue gas wet state＇s simultaneous desulfurization and denitration reactions respectively with Ca （OH）2 and CaCO3 , have both attained equilibrium, are then calculated. Calculation results show that as an absorbent, Ca（OH）2 is superior to CaCO3 , and both of them exhibit nearly a 100% removal efficiency. Figs 4,table 1 and refs 9.
出处
《动力工程》
EI
CSCD
北大核心
2006年第4期563-567,共5页
Power Engineering
基金
国家自然科学基金资助项目(50476059)
国家重点基础研究973发展规划资助项目(2006CB200303)
国家杰出青年科学基金资助项目(50525620)
关键词
环境工程学
脱硫脱硝
吸收特性
臭氧
environmental engineering
desulfurization and denitrification
absorbing characteristic
ozone
