摘要
采用电沉积方法，在含ＫＭｎｏ４的ＺｎＳＯ４溶液中，通过控电位和控电流，得到高择优取向的（０００２）和（１０１１）Ｚｎ沉积层．用Ｘ射线衍射技术和扫描电子显微镜进行表征．结果表明这种高择优取向的Ｚｎ沉积层与相应的Ｚｎ单晶具有相似的ＸＲＤ图，且具有比较完整的晶体结构，几乎不存在位错应力；还通过阴极极比曲线讨论了形成高择优取向Ｚｎ沉积层的可能原因．
Zn deposits with(0002)and(1011)highly preferred orientation were obtained in the solution of 0.8 mol/L ZnSO4,0.5 mol/L H2SO4 and 4.0×10-4 mol/LKMnO4 by controlling tlie deposition potential or current.The deposits with highly preferred orientation were studied by X-ray diffraction and scanning electron microscope.The results showed that tl1e diffraction patterns of the deposits with(0002)and(1011)highly preferred orientation were very similar to tlie corresponding patterns of Zn single crystals. But there were little disloction stresses in the deposits.The effort was made to explain the reason for the deposits with highly preferred orientation from the polarization curve of the solution.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1995年第1期87-90,共4页
Chemical Journal of Chinese Universities
基金
国家自然科学基金
关键词
电沉积
锌
织构
X射线衍射
Eleetrodeposited Zn,Texture,Highly preferred orientation,X-ray diffraction
