摘要
利用Ｃｕ（Ⅱ）吡啶能与酚形成稳定的三元配合物的特点，研究了Ｃｕ（Ⅱ）－吡啶－酚三元显色新体系，并以偏最小二乘法建立模型预测，同时测定了模拟水样和环境水样中的对苯二酚、间苯二酚、邻苯三酚和对硝基苯酚，取得满意效果。
Paradioxybenzene,resorcinol,pyrogallol and paranitrophenol can react with copper(Ⅱ)and pyridine to from stable ternary complexes, and the ternary chromogenic system has been studied. Principle of partial least squares was introduced. Results of simultaneous determination for multicomponent phenols compounds in mixed samples and environmental samples were predicted spctrophotometrically by partial least squares method.Predictive results and recovery are satisfactory.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1994年第9期1305-1308,共4页
Chemical Journal of Chinese Universities
基金
四川省教育委员会青年科学基金
关键词
偏最小二乘法
光度法
酚
多元体
Partial least squares method, Spectrophotometry,Simultaneous determination,Phenol
