Information on abundance and distribution of platinum\|group elements (PGE) in peridotite from ophiolite is relevant to understand the nature and evolution of the upper mantle. The ophiolite suite outcropping along th...Information on abundance and distribution of platinum\|group elements (PGE) in peridotite from ophiolite is relevant to understand the nature and evolution of the upper mantle. The ophiolite suite outcropping along the famous suture zone of Yarlung Zangbo River, Tibet, has attracted wide attention of geologists both in China and abroad. The Dagzhuka ophiolite of in the suture zone is thought to display a complete ophiolitic sequence. The peridotite from the Dazhuka ophiolite is composed of fairly fresh or unaltered lherzolite, harzburgite and minor dunite which are the upper mantle residuum formed by 15%～35% partial melting. In this paper we have mainly studied the abundance and distribution of PGE in the harzburgites and lherzolites. The harzburgites and lherzolites preserve total PGE contents of 28 37×10 -9 ～50 67×10 -9 respectively higher than Primitive mantle or the peridotite from some typical ophiolites and Alpine. They all have fractionated chondrite\|normalized PGE patterns with positive slopes from Ir to Pd (Fig.1), and Pd/Ir=1 13～2 40>1, Pd/Rh=2 23～7 49>1, and Pd/Pt=0 26～1 16 (average 0 67) higher than Primitive mantle (1 11, 2 35, 0 57) or CI\|chondrite (1 01, 2 73, 0 53). Consequently, the Dagzhuka peridotite are PGE\|enriched, but otherwise possess residual characteristics arising from a minimum of 15% partial melting. It is suggested that mantle residuum by partial melting have low total PGE contents, fractionated chondrite\|normalized PGE patterns with negative or slightly flat slopes from Ir to Pd, and Pd/Ir<1. But, the total PGE contents, chondrite\|normalized PGE patterns and Pt/Ir, Pd/Rh and Pd/Pt values of the Dagzhuka peridotite are completely inconsistent with a residual origin. Partial melting would have partitioned all sulfide in the source into the melt. In fact, no sulfide or silicate melt remained in the Dagzhuka peridotite. Therefore, PGE in Dagzhuka peridotite are not present in sulfides. The PGE\|enrichment and fractionation of the Dagzhuka peridotites seem to arise from mantle metasomatism of melts/fluid enrich incompatible elements include Pt and Pt, but not from residual or percolation of sulfides. The enrichment of Cs, Rb, Ba, Th, U and LREE in Dagzhuka peridotite also give a hint of the mantle metasomatism. The abundance and distribution of PGE in the peridotite from the Dagzhuka ophiolite show the nature and evolution of the Dagzhuka upper mantle are distinctive.展开更多
Numerous unique geological processes [1] took place during the early Earth evolution;several of them, especially those occurring in the Hadean—Early Archean and later, are reflected in the modern geological (geophysi...Numerous unique geological processes [1] took place during the early Earth evolution;several of them, especially those occurring in the Hadean—Early Archean and later, are reflected in the modern geological (geophysical, geochemical, etc.) pattern. One such significant enigmatic feature is the preservation of extremely dense and heavy platinum group elements (PGEs): Pt, Pd, Rh, Ru, Ir, Os. Concentration of PGEs during this period could have taken place in two ways: 1) presence of particular matter capable of preserving PGEs near the earth's surface, 2) transportation of PGEs by magma flows from deep lithospheric (asthenospheric) layers (slabs) to the subsurface. Clearly, much of the dense and heavy PGEs did not sink through to the Earth’s mantle (core) at the time of the magma-ocean, and occur near Earth’s surface in abundances for formation of ore deposits with PGE concentrations found to be 2 - 3 orders of magnitude greater than those in their host media. Their enrichments are associated in numerous cases with such enigmatic phenomena as formation of anorthosites and anorthosite-bearing layered magmatic intrusions. PGE deposits and mineralization zones are also found in associations with chromitites, dunites and serpentinites. In this review, problems related to the initial concentration and preservation of PGEs, their association with anorthosites, and formation of layered intrusions are discussed in detail. The main aim of this article is analysis of the requirements—initial concentration and preservation of PGE and PGM (Platinum Group Minerals) during the early Earth evolution, as well as examination of the distribution behavior of some PGEs in different ore deposits and meteorites. It is supposed that meteoritic bombardment of Earth has played a significant role in formation of PGEs deposits. Some conclusions made in this article may be useful for developing and enhancing strategies of prospecting for PGEs deposits.展开更多
The contents of the platinum-group elements (PGEs: Os, Ir, Ru, Rh, Pt, Pd) in the Abulangdang ultramafic intrusion have been determined using ICP-MS after nickel sulfide fire assay preconcentration. Different samples ...The contents of the platinum-group elements (PGEs: Os, Ir, Ru, Rh, Pt, Pd) in the Abulangdang ultramafic intrusion have been determined using ICP-MS after nickel sulfide fire assay preconcentration. Different samples show significant differences in absolute PGE abundance. They display a pronounced negative incline in mantle-normalized patterns which are characterized by strong enrichment in IPGEs (Os, Ir, Ru) and depleting to slight enrichment in PPGEs (Rh, Pt, Pd). The characteristics of PGE distribution in the Abulangdang rocks are due to the combined action of sulfide and non-sulfide (spinel/chromite or alloy or micro-granular aggregation of metals). In comparison with the mafic-ultramafic rocks which host Ni-Cu-PGE deposits in the Emeishan Large Igneous Province (ELIP), it is assumed that the Abulangdang ultramafic intrusion may be the product of early-stage magma activity in the ELIP.展开更多
The Meishucun section in Yunnan is the stratotype section for stratigraphic correlation of the Lower Cambrian strata across the Yangtze Block. Known for enriched small shelly fossils, it is a prominent section for inv...The Meishucun section in Yunnan is the stratotype section for stratigraphic correlation of the Lower Cambrian strata across the Yangtze Block. Known for enriched small shelly fossils, it is a prominent section for investigating the Early Cambrian phosphogenic event.Pasˇava et al.(Econ Geol 105:1047–1056, 2010) reported anomalously high PGE concentrations in this section, up to576 9 10-9(434 9 10-9Pt, 142 9 10-9Pd) for the total PGE concentrations of a K-bentonite sampled from the bottom of Bed 5. This finding can illustrate two significant statements:(1) in addition to the attested polymetallic NiMo-PGE ore layer, another potential PGE enrichment layer exists with PGE concentrations up to the mineralization level; and(2) acid volcanics have high PGE contents overturning conventional views. To inspect whether the anomalous PGE concentration is pervasive, we investigated Bed 5 of the Meishucun section systematically, and sampled from a profile with a thickness of 3.5 m. The major and trace element geochemistry indicate the Bed5 K-bentonite is derived from acid volcanic ash. PGE concentrations were determined repeatedly by isotope dilution-ICP-MS using improved digestion technique(Qi et al., in J Anal At Spectrom 26:1900–1904, 2011), and were duplicated by fire assay method. The results showed that each sample had total PGE concentrations of less than0.90 9 10-9, and Pt ? Pd concentrations of no higher than0.70 9 10-9. Combined with the petrological and mineralogical features, and trace and rare earth element analyses,it is inferred that no generality of PGE enrichment exists in Bed 5 and that the anomalous PGE concentration is likely due to the nugget effect of volcanic ash modified by currents in a shallow coastal environment.展开更多
文摘Information on abundance and distribution of platinum\|group elements (PGE) in peridotite from ophiolite is relevant to understand the nature and evolution of the upper mantle. The ophiolite suite outcropping along the famous suture zone of Yarlung Zangbo River, Tibet, has attracted wide attention of geologists both in China and abroad. The Dagzhuka ophiolite of in the suture zone is thought to display a complete ophiolitic sequence. The peridotite from the Dazhuka ophiolite is composed of fairly fresh or unaltered lherzolite, harzburgite and minor dunite which are the upper mantle residuum formed by 15%～35% partial melting. In this paper we have mainly studied the abundance and distribution of PGE in the harzburgites and lherzolites. The harzburgites and lherzolites preserve total PGE contents of 28 37×10 -9 ～50 67×10 -9 respectively higher than Primitive mantle or the peridotite from some typical ophiolites and Alpine. They all have fractionated chondrite\|normalized PGE patterns with positive slopes from Ir to Pd (Fig.1), and Pd/Ir=1 13～2 40>1, Pd/Rh=2 23～7 49>1, and Pd/Pt=0 26～1 16 (average 0 67) higher than Primitive mantle (1 11, 2 35, 0 57) or CI\|chondrite (1 01, 2 73, 0 53). Consequently, the Dagzhuka peridotite are PGE\|enriched, but otherwise possess residual characteristics arising from a minimum of 15% partial melting. It is suggested that mantle residuum by partial melting have low total PGE contents, fractionated chondrite\|normalized PGE patterns with negative or slightly flat slopes from Ir to Pd, and Pd/Ir<1. But, the total PGE contents, chondrite\|normalized PGE patterns and Pt/Ir, Pd/Rh and Pd/Pt values of the Dagzhuka peridotite are completely inconsistent with a residual origin. Partial melting would have partitioned all sulfide in the source into the melt. In fact, no sulfide or silicate melt remained in the Dagzhuka peridotite. Therefore, PGE in Dagzhuka peridotite are not present in sulfides. The PGE\|enrichment and fractionation of the Dagzhuka peridotites seem to arise from mantle metasomatism of melts/fluid enrich incompatible elements include Pt and Pt, but not from residual or percolation of sulfides. The enrichment of Cs, Rb, Ba, Th, U and LREE in Dagzhuka peridotite also give a hint of the mantle metasomatism. The abundance and distribution of PGE in the peridotite from the Dagzhuka ophiolite show the nature and evolution of the Dagzhuka upper mantle are distinctive.
文摘Numerous unique geological processes [1] took place during the early Earth evolution;several of them, especially those occurring in the Hadean—Early Archean and later, are reflected in the modern geological (geophysical, geochemical, etc.) pattern. One such significant enigmatic feature is the preservation of extremely dense and heavy platinum group elements (PGEs): Pt, Pd, Rh, Ru, Ir, Os. Concentration of PGEs during this period could have taken place in two ways: 1) presence of particular matter capable of preserving PGEs near the earth's surface, 2) transportation of PGEs by magma flows from deep lithospheric (asthenospheric) layers (slabs) to the subsurface. Clearly, much of the dense and heavy PGEs did not sink through to the Earth’s mantle (core) at the time of the magma-ocean, and occur near Earth’s surface in abundances for formation of ore deposits with PGE concentrations found to be 2 - 3 orders of magnitude greater than those in their host media. Their enrichments are associated in numerous cases with such enigmatic phenomena as formation of anorthosites and anorthosite-bearing layered magmatic intrusions. PGE deposits and mineralization zones are also found in associations with chromitites, dunites and serpentinites. In this review, problems related to the initial concentration and preservation of PGEs, their association with anorthosites, and formation of layered intrusions are discussed in detail. The main aim of this article is analysis of the requirements—initial concentration and preservation of PGE and PGM (Platinum Group Minerals) during the early Earth evolution, as well as examination of the distribution behavior of some PGEs in different ore deposits and meteorites. It is supposed that meteoritic bombardment of Earth has played a significant role in formation of PGEs deposits. Some conclusions made in this article may be useful for developing and enhancing strategies of prospecting for PGEs deposits.
基金supported by the National Natural Science Foundation of China (Grant Nos. 40573020 and 40773033)the Important Direction Program of the Chinese Academy of Sciences (Grant No. KZCX2-YW-111)
文摘The contents of the platinum-group elements (PGEs: Os, Ir, Ru, Rh, Pt, Pd) in the Abulangdang ultramafic intrusion have been determined using ICP-MS after nickel sulfide fire assay preconcentration. Different samples show significant differences in absolute PGE abundance. They display a pronounced negative incline in mantle-normalized patterns which are characterized by strong enrichment in IPGEs (Os, Ir, Ru) and depleting to slight enrichment in PPGEs (Rh, Pt, Pd). The characteristics of PGE distribution in the Abulangdang rocks are due to the combined action of sulfide and non-sulfide (spinel/chromite or alloy or micro-granular aggregation of metals). In comparison with the mafic-ultramafic rocks which host Ni-Cu-PGE deposits in the Emeishan Large Igneous Province (ELIP), it is assumed that the Abulangdang ultramafic intrusion may be the product of early-stage magma activity in the ELIP.
基金supported by National Science Foundation of China (Nos. 41072054, 40963002)
文摘The Meishucun section in Yunnan is the stratotype section for stratigraphic correlation of the Lower Cambrian strata across the Yangtze Block. Known for enriched small shelly fossils, it is a prominent section for investigating the Early Cambrian phosphogenic event.Pasˇava et al.(Econ Geol 105:1047–1056, 2010) reported anomalously high PGE concentrations in this section, up to576 9 10-9(434 9 10-9Pt, 142 9 10-9Pd) for the total PGE concentrations of a K-bentonite sampled from the bottom of Bed 5. This finding can illustrate two significant statements:(1) in addition to the attested polymetallic NiMo-PGE ore layer, another potential PGE enrichment layer exists with PGE concentrations up to the mineralization level; and(2) acid volcanics have high PGE contents overturning conventional views. To inspect whether the anomalous PGE concentration is pervasive, we investigated Bed 5 of the Meishucun section systematically, and sampled from a profile with a thickness of 3.5 m. The major and trace element geochemistry indicate the Bed5 K-bentonite is derived from acid volcanic ash. PGE concentrations were determined repeatedly by isotope dilution-ICP-MS using improved digestion technique(Qi et al., in J Anal At Spectrom 26:1900–1904, 2011), and were duplicated by fire assay method. The results showed that each sample had total PGE concentrations of less than0.90 9 10-9, and Pt ? Pd concentrations of no higher than0.70 9 10-9. Combined with the petrological and mineralogical features, and trace and rare earth element analyses,it is inferred that no generality of PGE enrichment exists in Bed 5 and that the anomalous PGE concentration is likely due to the nugget effect of volcanic ash modified by currents in a shallow coastal environment.
