High quality LiLuF4 single crystals doped with various Pr3+ ions were synthesized by a vertical Bridgman method in completely sealed platinum crucibles. The excitation spectra spans from 420 nm to 500 nm. The prepared...High quality LiLuF4 single crystals doped with various Pr3+ ions were synthesized by a vertical Bridgman method in completely sealed platinum crucibles. The excitation spectra spans from 420 nm to 500 nm. The prepared single crystals exhibit a blue band at 480 nm(3P0→3H4), a green band at 522 nm (3P1→3H5), and a red band at 605 nm (1D2→3H4)when excited at 446 nm;their corresponding average lifetimes are 38.5μs, 37.3μs, and 36.8μs, respectively, which are much longer than those in oxide single crystals. The effects of excitation wavelength and doping concentration on emission intensities and chromaticity coordinates are investigated. The optimal Pr3+ concentration is confirmed to be 0.5%.The temperature dependent emission shows that the emission intensity constantly decreases with the increase of temperature from 298 K to 443 K due to the enhancement of nonradiative quenching at high temperature. The 3P0→3H4 transition is the most vulnerable to temperature, followed by the 3P1→3H5 transition and 1D2→3H4 transition.展开更多
根据3μm连续激光产生机理和对基质材料要求,结合1.9μm和1.1μm激光二极管泵浦掺Ho^(3+)材料结果,采用1.1μm激光二极管泵浦Ho^(3+),Pr^(3+):Li Lu F4晶体,产生3μm激光。实验用泵源波长为1.140～1.150μm,带宽为5 nm,功率为0～10 W,...根据3μm连续激光产生机理和对基质材料要求,结合1.9μm和1.1μm激光二极管泵浦掺Ho^(3+)材料结果,采用1.1μm激光二极管泵浦Ho^(3+),Pr^(3+):Li Lu F4晶体,产生3μm激光。实验用泵源波长为1.140～1.150μm,带宽为5 nm,功率为0～10 W,光纤耦合输出;Ho^(3+),Pr^(3+):Li Lu F4晶体体积为3 mm×3 mm×30 mm,Ho^(3+)离子掺杂原子百分含量为2%,Pr^(3+)离子掺杂原子百分含量为0.6%;实验获得波长为2 934 nm连续激光输出,最大功率达到50 m W,斜率效率为22.6%,最大功率时,光束的质量M2因子约为4。展开更多
We report on the fast high-resohition study of LiLuF4：Tm3＋. The accurate energy level scheme of Tm3＋ in the LiLuF4 matrix was obtained for the 3H6.5.4, 3F4.3.2, and ^1G4 multiplets. It was shown that electric-dipol...We report on the fast high-resohition study of LiLuF4：Tm3＋. The accurate energy level scheme of Tm3＋ in the LiLuF4 matrix was obtained for the 3H6.5.4, 3F4.3.2, and ^1G4 multiplets. It was shown that electric-dipole transitions dominate for all the studied multiplets except the 3H5 one.展开更多
通过熔融法以及热处理,制备了Ce^(3+)掺杂含Li Lu F_4纳米晶的透明氟氧微晶玻璃。XRD结果表明,玻璃中析出的晶相为Li Lu F_4,其晶粒大小随热处理温度的升高和时间的延长而变大。在330 nm紫外光激发下,Ce^(3+)掺杂的氟氧玻璃和Li Lu F4...通过熔融法以及热处理,制备了Ce^(3+)掺杂含Li Lu F_4纳米晶的透明氟氧微晶玻璃。XRD结果表明,玻璃中析出的晶相为Li Lu F_4,其晶粒大小随热处理温度的升高和时间的延长而变大。在330 nm紫外光激发下,Ce^(3+)掺杂的氟氧玻璃和Li Lu F4微晶玻璃的发射为一峰值波长为370 nm的宽带光谱。微晶玻璃的发光强度显著高于未经过热处理的基础玻璃,并且随着热处理温度的升高及时间的延长,微晶玻璃的发光逐渐增强。微晶玻璃的370 nm发射的荧光寿命均长于基础玻璃的。展开更多
基金supported by the National Natural Science Foundation of China(No.51772159)the Natural Science Foundation of Zhejiang Province(No.LZ17E020001)K.C.Wong Magna Fund in Ningbo University
文摘High quality LiLuF4 single crystals doped with various Pr3+ ions were synthesized by a vertical Bridgman method in completely sealed platinum crucibles. The excitation spectra spans from 420 nm to 500 nm. The prepared single crystals exhibit a blue band at 480 nm(3P0→3H4), a green band at 522 nm (3P1→3H5), and a red band at 605 nm (1D2→3H4)when excited at 446 nm;their corresponding average lifetimes are 38.5μs, 37.3μs, and 36.8μs, respectively, which are much longer than those in oxide single crystals. The effects of excitation wavelength and doping concentration on emission intensities and chromaticity coordinates are investigated. The optimal Pr3+ concentration is confirmed to be 0.5%.The temperature dependent emission shows that the emission intensity constantly decreases with the increase of temperature from 298 K to 443 K due to the enhancement of nonradiative quenching at high temperature. The 3P0→3H4 transition is the most vulnerable to temperature, followed by the 3P1→3H5 transition and 1D2→3H4 transition.
基金supported by the National Natural Science Foundation of China(51272109)Natural Science Foundation of Ningbo City,China(201401A6105016,2013A610126)K.C.Wong Magna Fund in Ningbo University,China(NBUWC001)~~
文摘根据3μm连续激光产生机理和对基质材料要求,结合1.9μm和1.1μm激光二极管泵浦掺Ho^(3+)材料结果,采用1.1μm激光二极管泵浦Ho^(3+),Pr^(3+):Li Lu F4晶体,产生3μm激光。实验用泵源波长为1.140～1.150μm,带宽为5 nm,功率为0～10 W,光纤耦合输出;Ho^(3+),Pr^(3+):Li Lu F4晶体体积为3 mm×3 mm×30 mm,Ho^(3+)离子掺杂原子百分含量为2%,Pr^(3+)离子掺杂原子百分含量为0.6%;实验获得波长为2 934 nm连续激光输出,最大功率达到50 m W,斜率效率为22.6%,最大功率时,光束的质量M2因子约为4。
基金supported by the Russian Academy of Sciences under the grant of the Program "Quantum physics of condensed matter"the grant 09-02-01067-a of the Russian Foundation for Basic Research
文摘We report on the fast high-resohition study of LiLuF4：Tm3＋. The accurate energy level scheme of Tm3＋ in the LiLuF4 matrix was obtained for the 3H6.5.4, 3F4.3.2, and ^1G4 multiplets. It was shown that electric-dipole transitions dominate for all the studied multiplets except the 3H5 one.
文摘通过熔融法以及热处理,制备了Ce^(3+)掺杂含Li Lu F_4纳米晶的透明氟氧微晶玻璃。XRD结果表明,玻璃中析出的晶相为Li Lu F_4,其晶粒大小随热处理温度的升高和时间的延长而变大。在330 nm紫外光激发下,Ce^(3+)掺杂的氟氧玻璃和Li Lu F4微晶玻璃的发射为一峰值波长为370 nm的宽带光谱。微晶玻璃的发光强度显著高于未经过热处理的基础玻璃,并且随着热处理温度的升高及时间的延长,微晶玻璃的发光逐渐增强。微晶玻璃的370 nm发射的荧光寿命均长于基础玻璃的。
