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有机-无机混成材料改性聚氨酯性能研究
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作者 童建颖 卢玲 《化工生产与技术》 CAS 2006年第6期28-30,共3页
研究了以1-羟基聚丁二烯为基体的聚氨酯添加聚碳二亚胺(PCDI)和聚硅氧烷(PSi)改性为一种有机-无机混成材料。当分别添加5%的PSi及40%的PSi和聚甲基苯基硅氧烷(PMPS)所制得的绝热材质模数分别为33.4和90.0MPa,伸长率分别为62%和16%;经热... 研究了以1-羟基聚丁二烯为基体的聚氨酯添加聚碳二亚胺(PCDI)和聚硅氧烷(PSi)改性为一种有机-无机混成材料。当分别添加5%的PSi及40%的PSi和聚甲基苯基硅氧烷(PMPS)所制得的绝热材质模数分别为33.4和90.0MPa,伸长率分别为62%和16%;经热裂解后碳化层残留的质量分数增加0.7%~4%;升温速率与最大分解温度tm成线性关系,预计当燃料燃烧时升温速率为5000℃/min时,在氮气下tm分别为538℃和522℃。所得改性材料具有较高的模数和热稳定性。 展开更多
关键词 聚碳二亚胺 聚硅氧烷 1-羟基聚丁二烯 聚氨酯 混成材料 模数 热稳定性
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纳米碳管混成材料的合成与性质
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作者 林鸿明 陈正瀚 +2 位作者 林冠男 刘维人 魏碧玉 《武汉理工大学学报》 EI CAS CSCD 北大核心 2007年第10期113-115,共3页
纳米碳管自从1991年被饭岛澄男博士正式发现后,因为其特殊的结构与新奇的特性,已成为新世纪的梦幻材料,并对于人类的文明与生活添加了许多想象力与可能性。近几年,以纳米碳管为基础的纳米混成材料逐渐开始吸引研究人员的兴趣,其目标是... 纳米碳管自从1991年被饭岛澄男博士正式发现后,因为其特殊的结构与新奇的特性,已成为新世纪的梦幻材料,并对于人类的文明与生活添加了许多想象力与可能性。近几年,以纳米碳管为基础的纳米混成材料逐渐开始吸引研究人员的兴趣,其目标是利用纳米碳管的特性以开发出不同用途、特性更佳的新应用材料。针对纳米碳管混成材料的主要合成方法以及其新特性,介绍了其在各方面的应用。 展开更多
关键词 纳米碳管 混成材料 催化剂 场发射 气体感测
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改性聚氨酯混成耐烧蚀材料的研究 被引量:1
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作者 程宇 王素娟 《硅酸盐通报》 CAS CSCD 北大核心 2015年第8期2387-2391,2397,共6页
本研究目的是在于研制高碳化、高强度的耐烧蚀硅橡胶绝热层材料,以应用在整合式冲压引擎火箭(Integral Ramjet Rocket-IRR)当作热防护系统。Dow Corning DC93-104经Martin Martietta Aerospace推荐应用于此系统,是二种成份液态的硅橡胶... 本研究目的是在于研制高碳化、高强度的耐烧蚀硅橡胶绝热层材料,以应用在整合式冲压引擎火箭(Integral Ramjet Rocket-IRR)当作热防护系统。Dow Corning DC93-104经Martin Martietta Aerospace推荐应用于此系统,是二种成份液态的硅橡胶,高分子基体部份为含有硅乙烯(≡Si-C=C)官能基的甲基苯基聚硅氧烷(polymethylphenylsiloxane),以Pt系当催化剂,虽然DC93-104具有优异的耐烧蚀热特性,但烧蚀后形成高碳化的焦化层强度低,无法抵抗高速热气的冲刷而剥落,为改善此缺点只好在引擎室钢壳内部表面点焊数以千计不锈钢丝网目,于铸制绝热层时,让DC93-104胶料能穿插在各网目内,经由不锈钢丝网目以增强烧蚀后焦化层的强度,避免焦化层于引擎室二次燃烧时被高温、高压和高速热气流冲刷而剥落,以维热防护系统功能正常发挥。但是于引擎室钢壳内部表面点焊数以千计不锈钢丝网目是个耗时、费工的工作,所以本研究选用General Electric Co.二液型RTV 627及LSR 2650液态硅橡胶进行高碳化、高强度的耐烧蚀硅橡胶绝热层的开发,基由本身强度抵抗高温、高压和高速热气流冲刷而不剥落,如此即可节约成本也可以提升效率。 展开更多
关键词 改性聚氨酯 高碳化 耐烧蚀材料研究
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利用溶胶-凝胶法调节pH及添加PEG优化酒精纯化用SiO_2粉末(英文)
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作者 吴政宪 郑建星 +1 位作者 郑人豪 丁尚武 《波谱学杂志》 CAS CSCD 北大核心 2014年第1期7-19,共13页
该工作探讨利用TEOS前驱液及不同含量、不同分子量PEG制备出SiO2粉末的性质.SiO2粉末由溶胶-凝胶法制备,并结合退火前后烘干.TEOS前驱溶液的水解及缩合反应速率在pH=3时比在pH=5,7,9时进行得更彻底,且随温度及PEG分子量的升高而升高;粉... 该工作探讨利用TEOS前驱液及不同含量、不同分子量PEG制备出SiO2粉末的性质.SiO2粉末由溶胶-凝胶法制备,并结合退火前后烘干.TEOS前驱溶液的水解及缩合反应速率在pH=3时比在pH=5,7,9时进行得更彻底,且随温度及PEG分子量的升高而升高;粉末产率在TEOS前驱液pH=3时达到最大.与不加PEG的溶胶-凝胶法制备出的样品相比,加入PEG制备的粉末有更高的吸水能力.若粉末从高至500℃退火,则可发现乙醇浓度增加.依据液体和固体NMR、电子显微镜以及BET结果,对吸水及粉末表面积之间的关系进行了讨论. 展开更多
关键词 核磁共振(NMR) BET 电子显微镜(SEM) 多孔材料 有机-无机混成材料 酒精纯化 溶胶-凝胶法
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Preparation and Characterization of Organic/Inorganic Hybrid Nanofibers
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作者 吴宁 魏取福 +1 位作者 李琪 徐文正 《Journal of Donghua University(English Edition)》 EI CAS 2006年第5期20-23,共4页
A new class of nanocomposites based on organic and inorganic species integrated at a nanoscale has obtained more attention these years. Organic-inorganic hybrids have both the advantages of organic materials, such as ... A new class of nanocomposites based on organic and inorganic species integrated at a nanoscale has obtained more attention these years. Organic-inorganic hybrids have both the advantages of organic materials, such as light weight, flexibility and good moldability, and inorganic materials, such as high strength, heat stability and chemical resistance. In this work, PVAc/TiO2 organicinorganic hybrid was prepared by sol-gel process. Eiectrospinning technique was used to fabricate PVAc/TiO2 hybrid nanofibers. The structures and properties of the hybrid nanofibers were characterized by Scanning Electron Microscopy (SEM), Atomic Force Microscope (AFM), Differential Scanning Calorimeter (DSC) and Fouriertransform infrared (FTIR) spectra. SEM and AFM were employed to study the topography of the hybrid nanofibers. The chemical structure of the hybrid nanofibers were examined by FTIR. The DSC scans revealed the second order transition temperature of the hybrid materials were higher than PVAc. 展开更多
关键词 hybrid nano f ibers PVAc / TiO2 CHARACTERIZATION
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Multi-criteria Decision of Type and Building Material for Simple House Construction
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作者 Wahyu Wuryanti 《Journal of Civil Engineering and Architecture》 2013年第4期433-439,共7页
Facing the innovation technology in building construction, the designer has the option in selecting the type of system construction and building materials. There is a big question for the designer and owner on how to ... Facing the innovation technology in building construction, the designer has the option in selecting the type of system construction and building materials. There is a big question for the designer and owner on how to evaluate the quality material to meet the technical requirements as building construction reliability. By demand to provide a low cost house, there is need for improving structure model and material construction for residents. When material cost takes 60%-70% of total construction cost, it is important to select the appropriate building material. Currently the innovation of material building for main frame and wall component has present for residential projects in Indonesia. Attempt to replace the traditional material such as brick or pozzolan lime concrete block is developed a new material include utilization of coal combustion waste for concrete block, lightweight concrete, or prefab panel wall. This paper presents the research result to develop a tool support for material and system construction selecting that facilitates the selection an optimal material for a simple house construction. A multi-criteria decision method is used based on performance criteria such as economy, reliability, comfort and eco-friend. 展开更多
关键词 Multi-criteria decision building material simple house.
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Unprecedented Low-Cost Hybrid Material for CO2 and CH4 Separation
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作者 Murilo Pereira Moises Joziane Gimenes Meneguin +6 位作者 Cleiser Thiago Pereira da Silva Vicente Lira Kupfer Pedro Augusto Arroyo Andrelson Wellington Rinaldi Emerson Marcelo Girotto Silvia Luciana Favaro Eduardo Radovanovic 《Journal of Chemistry and Chemical Engineering》 2015年第5期318-323,共6页
The zeolite synthesis using waste as silicon source is a promising low-cost process. Sugarcane bagasse ash is a hazardous solid waste generated in large amounts in the sugar industry. Thus, development of new procedur... The zeolite synthesis using waste as silicon source is a promising low-cost process. Sugarcane bagasse ash is a hazardous solid waste generated in large amounts in the sugar industry. Thus, development of new procedures for its productive reuse is relevant. Therefore, this waste was used to prepare a new ZCNT (zeolite/carbon nanotube material). In this work, ZCNT was applied in a CO2/CH4 separation. The adsorption took place at 303 K under pressure of 0.1 until 20 bar and the data were fitted by Langmuir, Toth and Freundlich equations. The adsorbed amount at 20 bar found was 4.7 mmol of CO2/g and 4.1 mmol of CH4/g; at 3 bar the adsorbed amount was 4.1 mmol of COJg and 1.2 mmol of CHa/g. This result indicates that ZCNT has potential application in COJCH4 separation at low pressures. 展开更多
关键词 Gas adsorption biogas purification porous materials.
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