Most of phosphine halogen complexes of transition metals, platinum and palladium, possess catalytic properties. The configurations of Pt(Ⅱ) and Pd(Ⅱ) complexes are square planar, existing as cis and trans isomers. N...Most of phosphine halogen complexes of transition metals, platinum and palladium, possess catalytic properties. The configurations of Pt(Ⅱ) and Pd(Ⅱ) complexes are square planar, existing as cis and trans isomers. Nuclear magnetic resonance studies of the structures of phosphine complexes of platinum and palladium were reported, but no paper appeared on cyclopentyl phosphine except the ear-展开更多
文摘Most of phosphine halogen complexes of transition metals, platinum and palladium, possess catalytic properties. The configurations of Pt(Ⅱ) and Pd(Ⅱ) complexes are square planar, existing as cis and trans isomers. Nuclear magnetic resonance studies of the structures of phosphine complexes of platinum and palladium were reported, but no paper appeared on cyclopentyl phosphine except the ear-