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Hydrogenation of Alkenes with NaBH<sub>4</sub>, CH<sub>3</sub>CO<sub>2</sub>H, Pd/C in the Presence of O- and N-Benzyl Functions 被引量:3

Hydrogenation of Alkenes with NaBH<sub>4</sub>, CH<sub>3</sub>CO<sub>2</sub>H, Pd/C in the Presence of O- and N-Benzyl Functions
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摘要 NaBH<sub>4</sub>, CH<sub>3</sub>CO<sub>2</sub>H, Pd/C has been described as an effective reagent system to hydrogenate alkenes. Here, we show that the hydrogenation occurs chemoselectively, making it possible to hydrogenate alkenes under Pd/C catalysis with hydrogen created in situ without O- or N-debenzylation. NaBH<sub>4</sub>, CH<sub>3</sub>CO<sub>2</sub>H, Pd/C has been described as an effective reagent system to hydrogenate alkenes. Here, we show that the hydrogenation occurs chemoselectively, making it possible to hydrogenate alkenes under Pd/C catalysis with hydrogen created in situ without O- or N-debenzylation.
作者 Nuha Al Soom Thies Thiemann Nuha Al Soom;Thies Thiemann(Department of Chemistry, United Arab Emirates University, Al Ain, Abu Dhabi, United Arab Emirates)
出处 《International Journal of Organic Chemistry》 CAS 2016年第1期1-11,共11页 有机化学国际期刊(英文)
关键词 Alkene Hydrogenation Benzyl Ether Benzyl Ester N-Benzyl Group Alkene Hydrogenation Benzyl Ether Benzyl Ester N-Benzyl Group
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