期刊文献+

负载型Au催化剂的应用研究概述 被引量:3

Catalytic Performance of Gold Supported on Metal Oxide
在线阅读 下载PDF
导出
摘要 本文概述了Au催化剂的研究进展 ,各类反应对Au催化剂的微观结构非常敏感。催化剂的活性与载体的种类、催化剂表面Au晶粒大小、载体与Au相互作用的强弱以及制备方法密切相关。载体主要包括各种氧化物和分子筛 ;表面Au粒子平均直径小于 5nm ,一般会有较好的催化活性 ;常用沉积 -沉淀法或共沉淀法来制备。 A review on supported gold catalysts is given in this paper. Three factors are important in the catalysts, i.e., type of metal oxide supports, size of the gold particales and the strength of interaction between the gold particles and supports. Depostions-precipitation and co-precipitation are better methods than impregnation to prepare catalysts comprising fine gold particles and to provide the desired intimacy of contact between gold and supports. Low-temperature CO oxidation and propylene epoxidation over supported gold catalysts are discussed.
出处 《化学工业与工程》 CAS 2002年第6期462-466,共5页 Chemical Industry and Engineering
关键词 负载型 应用 研究 Au催化剂 沉积-沉淀法 一氧化碳 氧化 supported Au catalysts Au particles size CO oxdation Deposition-precipitation
  • 相关文献

参考文献18

  • 1KOZLOVA P, ASAKURA K, IWASAWA Y. Studies of gold species in iron-oxide-supported gold gatalyst derived from gold-phosphine complex Au(PPH3)(NO3) and as-precipitated wet Fe(OH)3[J].J Catal,1999,181(1):37-48.
  • 2PARK E D, LEE J S. Effects of pretreatment conditions on CO oxidation over supported Au catalysts [J]. J Catal,1999,186(1):1-11.
  • 3KOZLOV A I, KOZLOVA A P, LIU H, et al. A new approach to active supported Au catalysts [J]. Appl Catal A, 1999,182(1):9-28.
  • 4HAYASHI T, TANAKA K, HARUTA M, et al. Selective vapor-phase epoxidation of propylene over Au/TiO2 catalysts in the presence of oxygen and hydrogen [J]. J Catal, 1999,178(2):566-575.
  • 5BOND G C, THOMPSON D T. Catalysis by gold [J]. Catal Rev-Sci Eng, 1999,41(3,4):319-388.
  • 6STANGLAND E E, STAVENS K B, ANDRES R P, et al. Characterization of gold-titania catalyst via oxidation of propylene to propylene oxide [J]. J Catal, 2000,191:332-347.
  • 7YUAN Y, KOZLOVA A P, ASAKURA K, et al. Supported Au catalysts prepared from Au phosphine complexes and As-Precipitated metal hydroxides: characterization and low-temperature CO oxidation [J]. J Catal, 1997,170(1):191-199.
  • 8邹旭华,齐世学,贺红军,安立敦,段雪.不同方法制备的Au/Fe_2O_3催化剂对CO的催化氧化[J].烟台大学学报(自然科学与工程版),2000,13(3):171-175. 被引量:9
  • 9王桂英,余加佑,廉红蕾,李雪梅,贾明君,张文祥,吴通好,葛炎东.常温常湿CO氧化催化剂An/Fe_2O_3 的制备与稳定性研究[J].高等学校化学学报,2000,21(5):752-755. 被引量:17
  • 10IIZUKA Y, TODE T, TAKAO T, et al. A Kinetic and adsorption study of CO over unsupported fine gold power and over gold supported on titanium dioxide [J]. J Catal, 1999,187(1):50-58.

二级参考文献9

  • 1Liu H,J Catal,1999年,185卷,252页
  • 2Liu Z M,Catal Lett,1997年,43卷,51页
  • 3Zhang Wenxiang,Chem Res Chin Univ,1997年,13卷,3期,355页
  • 4HarutaM,YamadaN,KobaayashiT,etal.Coldcatalystspreparedbycoprecipitationforlow-temperatureoxidationofhydrogenandcarbonmonoxide[J].JCatal,1989,115:301~309.
  • 5HaoZP,AnLD,WangHL.SupportedgoldcatalystsforclosedcycleCO2laser[J].ChinChemLett,1995,(6):447~448.
  • 6YuanY,AsakuraK,WanH,etal.SupportedAucatalystspreparedfromAuphosphinecomplexesandas-precipitatedmetalhydroxides:characterizationandlow-temperatureCOoxidation[J].JCatal,1997,170:191~199.
  • 7MuetingAM,AlexanderBD,BoylePD,etal.Mixed-metal-goldphosphineclustercompounds[J].InorganicSyntheses,1992,29:280~281.
  • 8HarutaM.Size-andsupport-dependencyinthecatalysisofgold[J].CatalToday,1997,36:153~166. 2000-03-16
  • 9张文祥,陶玉国,贾明君,吴通好,李雪梅.不同方法制备的纳米Au/NiO上CO常温常湿催化氧化性能的研究[J].高等学校化学学报,1998,19(8):1317-1319. 被引量:22

共引文献24

同被引文献113

引证文献3

二级引证文献16

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部