摘要
Owing to their inherently excellent geometric structure[1-3]and applications in catalysis,luminescence,and biology[4-6],as well as their importance in gaining insights into the embryonic period of metal nanoparticles,large-bulk(nuclearity>50)atomprecise Ag nanoclusters(NCs)[2,7]have garnered significant attention.Recent advancements in the use of different thiol precursors as low-activity sulfur sources and the selection of appropriate anions(such as polyoxometalates and tetrahedral anions)have contributed to the development of large-sized Ag-S NCs with excellent properties[2].
基金
supported by the National Natural Science Foundation of China(92061201,92356304,and 22271258)
the Zhongyuan Thousand Talents(Zhongyuan Scholars)Program of Henan Province(234000510007),and Zhengzhou University
China National Postdoctoral Program for Innovative Talents(BX20230329)。
