摘要
New generation of lithium-ion batteries(LIBs)integrating solar energy conversion and storage is emerging,as they could solve the fluctuation problem in the utilization of solar energy.Photo-rechargeable lithium-ion batteries(PR-LIBs)are ideal devices for such target,in which solar energy is converted into electricity and stored in LIB.In order to achieve the high performance of PR-LIB,it is crucial to develop dual-function electrode materials that can synergistically capture solar energy and store lithium.Herein,we present photo-rechargeable lithium-ion batteries using defective black TiO_(2) as photoanode prepared by lithium reduction.The photoanode exhibits excellent photo response in full solar spectrum with a capacity enhancement of 46.4%under illumination,corresponding to the energy conversion efficiency of 4.4%at the current density of 1 A·g^(-1).When illumination is applied at 20 mA·g^(-1),the battery capacity increases from~230 in dark to~349 mAh·g^(-1) at the first cycle,and then stabilizes at 310 mAh·g^(-1),approaching the theoretical value of 335 mAh·g^(-1) of TiO_(2) electrode material.This finding provides thoughts for breaking the capacity limitations in TiO_(2) and paves the way for powering LIBs by solar illumination.
基金
support from Hefei National Laboratory for Physical Sciences at the Microscale,Hefei Science Center of Chinese Academy of Sciences,Fujian Institute of Innovation of Chinese Academy of Sciences,the National Key Research and Development Program of China(No.2021YFA1500402)
the National Natural Science Foundation of China(NSFC,Nos.21571167,51502282,and 22075266)
the Fundamental Research Funds for the Central Universities(Nos.WK2060190053 and WK2060190100).
