摘要
4-羟基-2,5-二甲基-3(2H)-呋喃酮(4-hydroxy-2,5-dimethyl-3(2H)-furanone,HDMF)是一种具有焦糖香的天然活性产物,在食品工业中具有极高的应用价值。该文对HDMF化学合成、美拉德反应、酶法催化、植物合成代谢以及微生物合成途径进行了全面阐述。化学合成为工业合成主要方法,但是存在原料价格昂贵、溶剂残留等问题;美拉德反应是热加工食品中形成HDMF的重要方式;植物合成代谢途径是农产品中形成HDMF的重要途径,形成路径较为清晰,但工业应用受到限制;微生物合成HDMF具有绿色可持续发展特性,但相关研究滞后,微生物代谢途径目前不清晰或存在争议,缺乏对关键底物、代谢途径及关键酶系等的基础认知,是今后利用微生物途径合成HDMF急需要解决的重要科学问题。
4-Hydroxy-2,5-dimethyl-3(2H)-furanone(HDMF)is a naturally active product with a strong caramel flavor,which is important for the food industry.In this paper,chemical synthesis,produce via the Maillard reaction,enzymatic catalysis,and plant and microbial synthesis of HDMF were reviewed.Chemical synthesis of furaneol is the main method of industrial synthesis,but there are problems such as costly materials and high residues.Maillard reaction and plant synthesis are important ways of HDMF in heated food and agricultural products.The formation path in the Maillard reaction and plant are relatively clear respectively,but they have not yet been used to control and utilize in industry production;Microbial synthesis of HDMF has the advantage of green and sustainable development,however research on it has fallen behind.The research on microbial metabolic pathways is unclear or controversial at present,with the lack of basic knowledge of key substrates,metabolic pathways,key enzymes,etc.It is an important scientific problem that needs to be urgently solved in the future to control and utilization of microbiology synthesis to product furaneol.
作者
俞兆斌
朱丽霞
YU Zhaobin;ZHU Lixia(School of Food Science and Engineering,Tarim University,Aral 843300,China;South Xinjiang Special Agricultural Products Deep Processing Corps Key Laboratory,Aral 843300,China)
出处
《食品与发酵工业》
CAS
CSCD
北大核心
2024年第4期329-336,共8页
Food and Fermentation Industries
基金
国家自然基金项目(32272457)。
关键词
呋喃酮
化学合成
美拉德反应
酶法合成
植物合成
微生物代谢
furaneol
chemical synthesis
Maillard reaction
enzymatic synthesis
plant synthesis
microbial synthesis
