摘要
1902年,瑞士化学家维尔纳对氯化铵结构的解释为氢键概念的形成奠定了基础。1920年,美国化学家拉提麦尔和罗德布什首先认识了水中的氢键:2个八隅体所持的氢核构成的“弱键(weak bond)”。1928年,美国化学家鲍林在解释[FHF]-的结构时首次使用“氢键(hydrogen bond)”一词,但并未对氢键的概念进行明确定义。1939年,鲍林在《化学键的本质》中明确提出了氢键的概念,并解释了氢键的性质,自此,氢键的概念正式形成。近年来,科学家经过深入研究发现了氢键的新类型:π型氢键、双氢键、金属氢键和单电子氢键。随着科学思想和科学技术的发展,关于氢键的认识也会越来越深入。
In 1902,the interpretation of the structure of ammonium chloride by the Swiss chemist Werner laid the foundation for the formation of the hydrogen bond concept. In 1920,American chemists Latimer and Rodebush first recognized the hydrogen bond in water and described it as a“weak bond”formed by the hydrogen nucleus held by two octets. In 1928,American chemist Pauling first used the term“hydrogen bond”when explaining the structure of [FHF]-,but did not clearly define the concept of hydrogen bond.In 1939,Pauling clearly put forward the concept of the hydrogen bond in The Nature of the Chemical Bond and explained the nature of the hydrogen bond. Since then, the concept of the hydrogen bond has been formally formed. In recent years, scientists have discovered new types of hydrogen bonds through in-depth research: π-type hydrogen bond, dihydrogen bond, metal hydrogen bond and single-electron hydrogen bond. With the development of scientific thought and technology, the understanding of the hydrogen bond will be more and more in-depth.
作者
胡琪琳
袁振东
HU Qi-Lin;YUAN Zhen-Dong(Institute of Chemistry and Chemical Engineering,Henan Normal University,Xinxiang 453007,China)
出处
《化学教育（中英文）》
CAS
北大核心
2023年第1期123-128,共6页
Chinese Journal of Chemical Education
关键词
氢键的概念
拉提麦尔
罗德布什
鲍林
氢键的新类型
concept of the hydrogen bond
Latimer
Rodebush
Pauling
new types of hydrogen bonds
