摘要
硫酰氟作为广谱的熏蒸剂和杀虫剂,性能优异,应用较为广泛。而其独特的物理化学性质,在有机合成化学中的应用近年来也被相继报道。通过对硫酰氟物理化学性质进行介绍,并且对合成硫酰氟的方法、生产情况进行了简要的总结归纳,同时对以硫酰氟作为反应物及化学反应中间体,在有机合成中用于构建磺酰氟、烷基胺、脱氢化等应用进行介绍。期望通过硫酰氟反应特性的介绍,为有机合成工作者提供硫酰氟更多的使用策略。
As a broad-spectrum fumigation agent and insecticide, sulfuryl fluoride has excellent functions and has been widely used.Due to the unique physical and chemical properties of sulfuryl fluoride, its application in organic synthetic chemistry has been reported successively in recent years.This work briefly introduces the physicochemical properties of sulfuryl fluoride, and summarizes the methods and production of the synthesis of sulfuryl fluoride, and makes a simple introduction to the application of sulfuryl fluoride as reactants and chemical reaction intermediates in organic synthesis for the construction of sulfonyl fluoride, alkylamine, dehydrogenation.It is expected that the introduction of the reactions of sulfuryl fluoride can provide more strategies for organic synthesis workers.
作者
姜雪峰
JIANG Xue-feng(Shanghai Key Laboratory of Green Chemistry and Chemical Process,School of Chemistry and Molecular Engineering,East China Normal University,Shanghai 200062,China)
出处
《化学试剂》
CAS
北大核心
2021年第4期454-457,共4页
Chemical Reagents
基金
国家自然科学基金资助项目(21971065)。
关键词
硫酰氟
点击化学
合成应用
氟磺酰咪唑盐
氟磺酰叠氮
sulfuryl fluoride
click chemistry
synthesis application
imidazolium fluorosulfuryl salt
fluorosulfuryl azide
