摘要
模拟金属材料在草酸钚沉淀母液蒸发浓缩工艺的服役条件,按GB/T 4334.3-2000要求,开展了含草酸的硝酸溶液对316L不锈钢板材和焊件的腐蚀行为研究。实验采用称重法获得了腐蚀速率数据,采用扫描电镜观察金属表面的腐蚀形貌,通过能谱分析腐蚀前后样品的表面元素分布,并测定了腐蚀溶液中金属离子的浓度。结果表明:模拟实验条件下316L不锈钢各腐蚀样品腐蚀速率较低,为均匀腐蚀。在103℃、8.0 mol/L硝酸条件下,316L不锈钢板材和焊缝的平均腐蚀速率分别为0.0496 g/(m^2·h)和0.0686 g/(m^2·h)。研究结果为草酸钚沉淀母液蒸发浓缩设备的材料选择提供了数据参考,优化焊缝工艺是316L不锈钢作为草酸母液蒸发浓缩设备材料使用重要的改进方向。
In this work,the service environment of metal materials used in the evaporation and concentration process of the mother liquor after plutonium oxalate precipitation was simulated,and the corrosion behavior of 316L stainless steel plate and its welding samples in the mixed oxalic-nitric acid was studied according to the requirements of GB/T 4334.3-2000.The corrosion rates were obtained by weighting method,and the corrosion morphology of metal surface was observed by scanning electron microscope,and the distributions of surface elements before and after corrosion were analyzed by energy spectrum,and the concentrations of metal ions in the corrosion solutions were determined.The results show that the corrosion rates acquired by simulating corrosion tests are relatively low,and the corrosion is uniform.The average corrosion rates of 316L stainless steel plate in 8.0 mol/L nitric acid at 103℃ are 0.0496 g/(m^2·h)for plate and 0.0686 g/(m^2·h)for weld respectively.The research results provide data reference for the material selection of the equipment used in the evaporation and concentration process of the mother liquor after plutonium oxalate precipitation.The optimization of welding process is an important improvement direction for the use of 316L stainless steel as this equipment.
作者
郭建华
何辉
刘金平
申震
叶国安
李高亮
GUO Jian-hua;HE Hui;LIU Jin-ping;SHEN Zhen;YE Guo-an;LI Gao-liang(China Institute of Atomic Energy,P.O.Box 275(26),Beijing 102413,China)
出处
《核化学与放射化学》
CAS
CSCD
北大核心
2020年第5期336-343,I0002,共9页
Journal of Nuclear and Radiochemistry
关键词
乏燃料后处理
316L不锈钢
草酸
腐蚀
spent fuel reprocessing
316L stainless steel
oxalic acid
corrosion
