摘要
以活性白土为载体,硝酸镍和钼酸铵为原料,采用等体积法浸渍与CS2原位活化法相结合的方法制备硫化型Ni-Mo双金属/活性白土(NiMoS/活性白土)催化剂。以麻疯树油转化率和生成C15~C18烃类的选择性为主要性能指标,考察各制备因素对催化性能的影响。确定最佳制备工艺条件为:NiO负载量12%、MoO3负载量14%、焙烧温度450℃、焙烧时间175 min、硫化初始氢压3 MPa、硫化剂用量16 mol/mol、硫化温度320℃、硫化时间60 min。制备的NiMoS/活性白土能将麻疯树油中的主要成分加氢催化裂解多种长链烯烃,制备出第二代生物柴油。
By isovolumetric impregnation and CS2 in situ activation method,a sulfurated NiMo/activated clay catalyst was prepared using activated clay as carrier and nickel nitrate and ammonium molybdate as raw materials.With conversion of jatropha oil and selectivity to C15-C18 as the indexes,the effect of various preparation factors on the catalytic property of sulfurated NiMo/activated clay was investigated.The optimum preparation conditions were as follows:NiO load 12%,MoO3 load 14%,calcination temperature 450℃,calcination time 175 min,initial hydrogen pressure of sulfide 3 MPa,dosage of vulcanizer 16 mol/mol,sulfuration temperature 320℃ and sulfuration time 60 min.Catalyzed by the as-prepared catalyst,Jatropha oils were successfully converted into various long chain alkenes of second-generation biodiesel through the catalytic hydro-deoxgeneation reaction.
作者
杨艳娟
高磊
王艺志
魏光涛
辛宗武
李仲民
张琳叶
施冰梅
Yang Yanjuan;Gao Lei;Wang Yizhi;Wei Guangtao;Xin Zongwu;Li Zhongmin;Zhang Linye;Shi Bingmei(School of Chemistry and Chemical Engineering,Guangxi University,Nanning,Guangxi 530004)
出处
《非金属矿》
CAS
CSCD
北大核心
2020年第2期23-26,共4页
Non-Metallic Mines
基金
国家自然科学基金(21667004)
广西自然科学基金(2018GXNSFAA138039,2018GXNSFAA281343)
广西大学大学生创新创业训练计划项目(201910593176)。
关键词
活性白土
催化剂
生物柴油
植物油
加氢
activated clay
catalyst
biodiesel
plant oils
hydrogenation
