摘要
简要介绍磷系阻燃剂、笼型倍半硅氧烷(POSS)和磷系阻燃剂/POSS的阻燃机理.重点概述了近些年来磷系阻燃剂/POSS复配体系在阻燃聚对苯二甲酸乙二醇酯(PET)中应用的研究进展情况,其中主要包括磷腈类阻燃剂/POSS复配体系、无机磷酸盐类/POSS体系以及DOPO/POSS体系对PET的阻燃研究进展.为进一步开发高效、廉价、环保的商用PET阻燃剂提供理论支撑.
In this paper,the flame retardant mechanism of phosphorus series flame retardants,cage sesquioxane(POSS)and phosphorus series flame retardants/POSS are briefly introduced.The application and research progress of phosphorus flame retardant/POSS compound system in antiflaming polyethylene terephthalate(PET)in recent years were reviewed,including the phosphonitrile flame retardant/POSS compound system,inorganic phosphate/POSS system and DOPO/POSS system.It provides theoretical support for the further development of efficient,cheap and environment-friendly commercial PET flame retardant.
作者
马晓涛
周筱雅
方铖
徐莹莹
茅琪婧
Juraev Mansurjon
叶锋
MA Xiaotao;ZHOU Xiaoya;FANG Cheng;XU Yingying;MAO Qijing;JURAEV Mansurjon;YE Feng(School of Textile and Apparel Engineering,Shaoxing University,Shaoxing,Zhejiang 312000;Key Laboratory of Clean Dyeing and Finishing Technology of Zhejiang Province,Shaoxing,Zhejiang 312000)
出处
《绍兴文理学院学报》
2020年第2期84-90,共7页
Journal of Shaoxing University
基金
国家自然科学基金项目“POSS核树枝状大分子/碳纳米管杂化凝胶的制备、自组装机理及改性聚合物的研究”(51703129)
浙江省公益技术研究项目“新型稀土抗菌复合热稳定剂的开发及其在聚氯乙烯纤维中的应用研究”(LGG20E030003)
绍兴市公益性技术应用研究计划项目“新型环保抗菌热稳定剂的开发及其对聚氯乙烯纤维的改性应用研究”(2017B70045)
大学生科技创新项目“POSS为基的阻燃剂改性PET纤维阻燃性能的研究”(2018R432026)
大学生科技创新项目“对新型POSS改性WPU为主的纯棉织物的阻燃涂层剂的阻燃性能研究”(2019R432017).
关键词
PET
POSS
磷系阻燃剂
协同效应
研究进展
PET
POSS
phosphorus flame retardant
synergistic effect
research progress
