摘要
A new nanostructured amino-functionalized magnetic bacterial cellulose/activated carbon（BC/AC）composite bioadsorbent（AMBCAC）was prepared for removal of Pb^2＋ and methyl orange（MO）from aqueous solution.The results demonstrated that the equilibrium adsorption capacity（qe）for Pb^2＋ obviously increases by 2.14 times after introduction of amino groups,the optimum p H for Pb^2＋and MO adsorption was 5.0 and 3.0,respectively,and the qeof AMBCAC was 161.78 mg g^-1 for Pb^2＋ and 83.26 mg g^-1 for MO under the optimal conditions in this investigation.The kinetics and adsorption isotherm data of the sorption process were well fitted by pseudo-second-order kinetic model and Langmuir isotherm respectively.The thermodynamic results（the Gibbs free energy change G〈0,the enthalpy change H〉0,the entropy change S〉0）implied that the adsorption process of Pb^2＋ and MO was feasible,endothermic and spontaneous in nature.These results support that the AMBCAC composite developed in this work can provide a cheap and efficient way for easy removal of both Pb^2＋ and MO as a promising adsorbent candidate for wastewater treatment.
A new nanostructured amino-functionalized magnetic bacterial cellulose/activated carbon（BC/AC）composite bioadsorbent（AMBCAC）was prepared for removal of Pb^2＋ and methyl orange（MO）from aqueous solution.The results demonstrated that the equilibrium adsorption capacity（qe）for Pb^2＋ obviously increases by 2.14 times after introduction of amino groups,the optimum p H for Pb^2＋and MO adsorption was 5.0 and 3.0,respectively,and the qeof AMBCAC was 161.78 mg g^-1 for Pb^2＋ and 83.26 mg g^-1 for MO under the optimal conditions in this investigation.The kinetics and adsorption isotherm data of the sorption process were well fitted by pseudo-second-order kinetic model and Langmuir isotherm respectively.The thermodynamic results（the Gibbs free energy change G〈0,the enthalpy change H〉0,the entropy change S〉0）implied that the adsorption process of Pb^2＋ and MO was feasible,endothermic and spontaneous in nature.These results support that the AMBCAC composite developed in this work can provide a cheap and efficient way for easy removal of both Pb^2＋ and MO as a promising adsorbent candidate for wastewater treatment.
基金
supported financially by the National Natural Science Foundation of China (No.51301039)
the Natural Science Foundation of Fujian Province (No.2016J01214)
the Public Institutes Special Fund Project of Fujian Province (No.2016R10096)
