摘要
综述了近年来具有对位芳酮选择性的Friedel-Crafts酰基化反应催化剂的发展前沿及应用情况。其催化剂主要有Lewis酸、固载型AlCl3催化剂、离子液体、沸石分子筛、杂多酸、超强酸等,重点介绍了离子液体、沸石分子筛、杂多酸、固体超强酸、金属氧化物的研究进展。提出对未来开发新型Friedel-Crafts酰基化催化剂的发展趋势。
The development and application of Friedel-Crafts acylation reaction catalyst with the selectivity of para aromatic ketone in recent years are reviewed. The catalysts mainly include Lewis acid, solid supported AlCl3 catalyst, ionic liquid, zeolite molecular sieve, heteropoly acid, superacid and so on. This paper focuses on the research progress of ionic liquids, zeolitic molecular sieves, heteropoly acids, solid superacids and metal oxides. Finally, the development tendency of new Friedel-Crafts acylation catalyst is put forward.
作者
闫义彬
王登飞
任合刚
李凌飞
徐用军
Yan Yibin Wang Dengfei Ren Hegang Li Lingfei Xu Yongjun(School of Chemical Engineering ＆ Technology, Harbin Institute of Technology, Harbin 150001, Heilongjiang, China Daqing Petrochemical Research Center, Petrochemical Research Institute of CNPC Daqing 163714, Heilongjiang, China)
出处
《精细石油化工》
CSCD
北大核心
2017年第4期75-80,共6页
Speciality Petrochemicals
关键词
酰基化反应
对位芳酮
离子液体
沸石分子筛
杂多酸
固体超强酸
acylation reaction
p-aromatic ketone
ionic liquid
zeolite molecular sieve
heteropoly acid
solid superacid
