摘要
用三苯基氯化锡与 2 噻吩甲酸钠反应 ,合成了三苯基锡 2 噻吩甲酸酯 ,并进行了红外光谱、核磁共振氢谱及质谱表征 .X射线单晶衍射表明 ,化合物属单斜晶系 ,空间群P2 1/n ,晶胞参数 :a =1 34 2 9(7)nm ,b =1 11773(6 )nm ,c=1 42 41(8)nm ,β =116 5 19(6 )° ,V =2 0 146 (18)nm3 ,Z =4,Dc=1 5 73g/cm3 ,R1=0 0 391,wR2 =0 0 943.该化合物的晶体是由孤立的分子所组成 ,四配位的锡原子呈畸变的四面体构型 。
Triphenyltin 2-thiophenecarboxylate was synthesized by reaction of sodium 2-thiophenecarboxylate and characterized by IR, 1H NMR and MS spectroscopy. The crystal structure was determined by X-ray single crystal diffraction study. The compound crystallizes in monoclinic space group P2 1/n, with a=1.3429(7) nm, b=1.11773(6) nm, c=1.4241(8) nm, β=116.519(6)°, V=2.0146(18) nm 3, Z=4, D c=1.573 g/cm 3, R 1=0.0391, wR 2=0.0943. In unit, there are four-coordinate tin atoms in a distorted tetrahedral configuration.
出处
《有机化学》
SCIE
CAS
CSCD
北大核心
2002年第8期590-593,共4页
Chinese Journal of Organic Chemistry
基金
教育部骨干教师基金
山东省自然科学基金 (No .Z2 0 0 1B0 2 )资助项目
