摘要
含能材料的研究已进入富氮化合物阶段.在富氮化合物的母体结构中,三唑母体含氮量较高,且三唑分子结构中存在较多的氮氢元素,使得分子内及分子间易形成氢键,提高了化合物的稳定性.论文综述了近年来国内外对氨基三唑、硝基三唑、叠氮三唑和偶联三唑的合成、表征以及性能方面的研究进展.最后对三唑含能化合物的发展趋势和应用前景做了期许和展望,提出在理论探讨、简易合成路线和新结构的三唑化合物3个方面是今后研究的方向.这对三唑类化合物在含能材料领域的推广和应用非常必要.
Research of energetic material has entered a stage of nitrogen-rich compound. In the matrix structure of nitrogen-rich compound, triazole matrix contains high nitrogen, and there are much nitrogen and hydrogen existing in triazole molecular structure, which make the intramolecular and intermolecular easy to form hydrogen bond. This improves the stability of the compound. The research progress of the synthesis, characterization and performance about amino triazole, nitro triazole and coupling triazole at home and abroad in recent years was reviewed. At last, the development trends and application prospects of triazole compounds were discussed and excepted. The deeper theory study, simple synthesis route and the new triazole compounds are the direction of future research. They are very necessary for triazole compounds in the promotion and application in the field of energetic material.
出处
《北京理工大学学报》
EI
CAS
CSCD
北大核心
2016年第6期551-557,共7页
Transactions of Beijing Institute of Technology
关键词
三唑
富氮化合物
含能材料
triazole
nitrogen-rich compound
energetic material
