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An experimental determination of W,Nb,and Ta partition coefficients between P-rich peraluminous granitic melt and coexisting aqueous fluid 被引量:1

An experimental determination of W,Nb,and Ta partition coefficients between P-rich peraluminous granitic melt and coexisting aqueous fluid
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摘要 The partition coefficients of W,Nb,and Ta between the P-rich peraluminous granitic melt and the coexisting aqueous fluid were determined at 800-850 °C and 0.5-1.5 kbar.The experimental results showed that the partition coefficients D_w,D_(Nb) and D_(Ta)(D_i^(v/m) = C_i^V/C_i^m,where C_i^V and C_i^m denote the concentrations of an element,i,in the aqueous fluid and the melt,respectively) were less than 0.1.All partition coefficients were affected by pressure,but there was no evidence for the complexation of P2O5 with these elements in the granitic melt or aqueous fluid,except for with W in the fluid.The results showed that W,Nb,and Ta tended to partition into the granitic melt and,in the late period of crystallization of P-rich magma,they formed independent minerals. The partition coefficients of W,Nb,and Ta between the P-rich peraluminous granitic melt and the coexisting aqueous fluid were determined at 800-850 °C and 0.5-1.5 kbar.The experimental results showed that the partition coefficients Dw,D(Nb) and D(Ta)(Di^v/m = Ci^V/Ci^m,where Ci^V and Ci^m denote the concentrations of an element,i,in the aqueous fluid and the melt,respectively) were less than 0.1.All partition coefficients were affected by pressure,but there was no evidence for the complexation of P2O5 with these elements in the granitic melt or aqueous fluid,except for with W in the fluid.The results showed that W,Nb,and Ta tended to partition into the granitic melt and,in the late period of crystallization of P-rich magma,they formed independent minerals.
出处 《Chinese Journal Of Geochemistry》 EI CAS CSCD 2015年第2期194-200,共7页 中国地球化学学报
基金 supported by the Chinese National Natural Science Foundation(Project No.40273030) the Chinese Academy of Sciences through an innovation project (Project No.KZCX3-SW-124)
关键词 分配系数 实验测定 水流体 过铝质 熔体 NB 共存 Partition coefficient P-rich granitic melt Fluid
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