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Thermodynamic analysis of the compositional control of inclusions in cutting-wire steel 被引量:2

Thermodynamic analysis of the compositional control of inclusions in cutting-wire steel
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摘要 Data from a thermodynamic database and the calculation software FactSage were used to investigate the phase diagrams of the MnO?CaO?SiO2?Al2O3 system in cutting-wire steel and the effects of oxide components on the low-melting-point (LMP) zone in the cor-responding phase diagrams. Furthermore, the activities of oxide components in the quaternary system at an Al2O3 content of 25wt%were calculated. The contents of dissolved [Al] and [O] in liquid steel in equilibrium with LMP inclusions in the MnO-CaO-SiO2-Al2O3 system were optimized. The results show that the MnO-CaO-SiO2-Al2O3 system possesses the largest LMP zone (below 1400℃) at an Al2O3 content of 25wt%and that the CaO content should be simultaneously controlled in the range of 40wt%to 45wt%. The activities of the oxide components CaO, MnO, and SiO2 should be restricted in the ranges of 0 to 0.05, 0.01 to 0.6, and 0.001 to 0.8, respectively. To obtain LMP inclusions, the [Al] and [O] contents in cutting-wire steel must be controlled within the ranges of 0.5 ×10^-6 to 1.0 ×10^-5 and 3.0 ×10^-6 to 5.0 × 10^-5, respectively. Data from a thermodynamic database and the calculation software FactSage were used to investigate the phase diagrams of the MnO?CaO?SiO2?Al2O3 system in cutting-wire steel and the effects of oxide components on the low-melting-point (LMP) zone in the cor-responding phase diagrams. Furthermore, the activities of oxide components in the quaternary system at an Al2O3 content of 25wt%were calculated. The contents of dissolved [Al] and [O] in liquid steel in equilibrium with LMP inclusions in the MnO-CaO-SiO2-Al2O3 system were optimized. The results show that the MnO-CaO-SiO2-Al2O3 system possesses the largest LMP zone (below 1400℃) at an Al2O3 content of 25wt%and that the CaO content should be simultaneously controlled in the range of 40wt%to 45wt%. The activities of the oxide components CaO, MnO, and SiO2 should be restricted in the ranges of 0 to 0.05, 0.01 to 0.6, and 0.001 to 0.8, respectively. To obtain LMP inclusions, the [Al] and [O] contents in cutting-wire steel must be controlled within the ranges of 0.5 ×10^-6 to 1.0 ×10^-5 and 3.0 ×10^-6 to 5.0 × 10^-5, respectively.
出处 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2014年第7期647-653,共7页 矿物冶金与材料学报(英文版)
关键词 wire steel CURING INCLUSIONS thermodynamic calculations ACTIVITY OXIDES wire steel curing inclusions thermodynamic calculations activity oxides
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