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食用油脂中GEs的生成机制及其检测方法研究进展 被引量:6

The Generative Mechanism and Detection Methods of GEs in Edible Oils-a Review
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摘要 缩水甘油酯是在油脂精炼加工过程中产生的一种污染物,其本身并不具致癌性,然而其在人体中易分解代谢产生具有致癌性的3-氯丙二醇酯。因此,精炼食用油脂中的缩水甘油酯可能会引起食品安全问题。文章对缩水甘油酯的生成机制、安全风险及控制手段进行了综述,并对其检测方法进行了比较和探讨。 The glycidyl esters are one of the pollutants in refined edible oils which generated from the refining process. Although glycidyl esters do not possess carcinogenicity, it could easily decompose to generate the cancerogen 3-chlorine propylene glycol ester through metabolism. Therefore, the glycidyl esters in refined edible oils may cause problem of food safety. In this paper, the generative mechanism, food risk and control methods of glycidyl esters were reviewed. In addition, the detection approaches of glycidyl esters had been compared in this review.
出处 《广东化工》 CAS 2014年第14期129-130,共2页 Guangdong Chemical Industry
关键词 缩水甘油酯 食用油脂 生成机制 检测方法 glycidyl esters edible oils generative mechanism detection method
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参考文献12

  • 1陈华勇,唐小红,王永华,杨博.GC-MS定性分析食用油中的缩水甘油酯有害物[J].中国油脂,2012,37(3):66-69. 被引量:6
  • 2Svejkovska B, Dolezal M, Velisek J. Formation and decomposition of 3-chloropropane-1,2-diol esters in models simulating processed foods[J]. Czech JournalofFoodScience, 2006, 24(4): 172-179.
  • 3周红茹,金俊,杨娇,金青哲.油脂中3-氯丙二醇酯形成的化学反应机制[J].中国粮油学报,2012,27(10):118-122. 被引量:17
  • 4Hamlet C G, Sadd P A, Crews C, et al. Occurrence of 3-chloro-propane-l,2-diol (3-MCPD) and related compounds in foods: a review[J]. Food Additives and Contaminants, 2002, 19(7): 619-631.
  • 5Honda H, Onishi M, Fujii K, et al. Measurement ofglycidol hemoglobin adducts in humans who ingest edible oil containing small amounts of glycidol fatty acid esters[J]. Food and Chemical Toxicology, 2012, 49: 2536-2540.
  • 6Honda H, Fujii K, Yamaguchi T, et al. Glycidol exposure evaluation of humans who have ingested diacylglycerol oil containing glycidol fatty acid esters using hemoglobin adducts[J]. Food and Chemical Toxicology, 2012, 50: 4163-4168.
  • 7Ikeda N, Fujii K, Sarada M, et al. Genotoxicity studies of glycidol fatty acid ester (glycidol linoleate) and glycidol[J]. Food and Chemical Toxicology, 2012, 50: 3927-3933.
  • 8Masukawa Y. A new analytical method for the quantification of glycidol fatty acid esters in edible oils[J]. Journal of Oleo Science, 2010, 59 (2): 81-88.
  • 9Masukawa Y. Generalized method to quantify glycidol fatty acid esters in edible oils [J]. Journal of the American Oil Chemists' Society, 2011, 88: 15-21.
  • 10Shiro H. Direct method for quantification of glycidol fatty acid esters in edible oils [J]. European Journal of Lipid Science and Technology, 2011, 113 : 356-360.

二级参考文献22

  • 1柳洁,何碧英,孙俊红.氘代同位素内标GC/MS法测定食品中3-氯-1,2-丙二醇的方法研究[J].中国卫生检验杂志,2005,15(4):392-395. 被引量:5
  • 2C. G. Hamlet, P. A. Sadd, C. Crews, et al. Occurrence of 3- chloro-propane-1,2-diol (3-MCPD)and related compounds in foods: a review [J] . Food Additives & Contaminants: Part A, 2002, 19 (7): 619-631.
  • 3Zelinkova Z., Svejkovsk6 B., Velfnek J., et al. Fatty acid esters of 3-chloropropane-1,2-diol in edible oils [J] .Food Additives & contaminants: Part A, 2006, 23 (12): 1290-1298.
  • 4Seefelder W., Varga N., Studer A., et al. Esters of 3-chloro-1,2- propanediol (3-MCPD) in vegetable oils: Significance in the for- mation of 3-MCPD [J] . Food Additives & Contaminants: Part A, 2007, 25 (4): 391-400.
  • 5Zuzana Zelinkova, Marek Doleqal, Jan Vellnek. Occurrence of 3- chloropropane-1,2-diol fatty acid esters in infant and baby foods [J]. Eur Food Res Technol, 2009 (228): 571-578.
  • 6DGF Standard Methods C-Ⅲ 18 (09) . Ester-bound 3-ehloro- propane-1,2-diol (3-MCPD esters) and glycidol (glycidyl esters) Determination in fats and oils by GC-MS [S] .
  • 7MAERKER G,CARMICHAEL J F,PORT W S.GlycidylestersⅠ.method of preparation and study of some reactionvariables[J].J Org Chem,1961,26(8):2681-2688.
  • 8MAERKER G,SAGGESE E J,PORT W S.Glycidyl estersⅡ.synthesis of esters of commercial and pure fatty acids[J].J Am Oil Chem Soc,1961,38(4):194-197.
  • 9WEIβHAAR R.Determination of total 3-chloropropane-1,2-diol(3-MCPD)in edible oils by cleavage of MCPDesters with sodium methoxide[J].Eur J Lipid Sci Techn-ol,2008,110(2):183-186.
  • 10HAINES T D,ADLAF K J,PIERCEALL R M,et al.Dierctdetermination of MCPD fatty acid esters and glycidyl fattyacid esters in vegetable oils by LC-TOFMS[J].J Am OilChem Soc,2011,88(1):1-14.

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