摘要
难选锡中矿经高温氯化制得的氯化焙球中各有色金属含量符合要求 ,但其抗压强度较低 ,达不到高炉炼铁的要求 .为提高氯化焙球的抗压强度 ,对难选锡中矿氯化焙球的高温氧化固结进行了研究 ,考察了氧化固结温度、恒温时间、气氛和升温速度等对氯化焙球氧化固结时强度的影响 ,获得了最佳的固结条件 :温度 12 0 0℃ ,恒温时间 3 5min ,氧化气氛中氧的质量分数 10 %～ 12 % ,升温速度 8～ 9℃ /min .在最佳条件下 ,获得的氧化焙球中铁的质量分数达 4 0 %以上 ,其它各有色金属的质量分数分别为 :w(Sn) <0 .0 2 % ,w(Pb) <0 .0 2 % ,w(As) <0 .0 5 % ,w(Zn) <0 .0 4 % ,w(Cu) <0 .18% ,而且氧化焙球的抗压强度达到了 15 0 0Pa左右 。
The contents of non ferrous metals in chloratized roasted pellet were perfect, but the compression strength was not up to grade. The oxidation solidification of chloratized roasted pellet obtained from chloration volatilization of difficult to separate tin middling mine was studied in details, so as to enhance the compression strength. Several parameters such as temperature, the time of constant temperature, atmosphere, the speed of temperature elevation and so on were investigated respectively, and then the optimum conditions were obtained as follows: temperature was 1 200 ℃, constant time was 35 min, the content of O 2 in atmosphere was 10%～12%(mass fraction) and the speed was 8～9 ℃/min. Under the optimum conditions, the content of Fe in the oxidized roasted pellet was more than 40%, the other main non ferrous metals contents were w(Sn)<0.02%, w(Pb)<0.02%, w(As)<0.05%, w(Zn)<0.04%, w(Cu)<0.18%,and the average compression strength of oxidized roasted pellet is 1 500 Pa, which could satisfy the needs of blast furnace.
出处
《中南工业大学学报》
CSCD
北大核心
2001年第4期363-366,共4页
Journal of Central South University of Technology(Natural Science)
基金
湖南省科委科研基金资助项目 ( 97JKN2 0 2 1)
关键词
锡中矿
氯化焙球
氧化固结
抗压强度
氧化球团强度
tin middling mine
chloratized roasted pellet
oxidation-solidification
compression strength
