摘要
为了探究硫代双烯金属络合物的金属原子对化合物性能的影响,本文设计并合成了一个含长碳链的硫代双烯钴络合物的近红外染料,考察其光热性能,并与镍硫代双烯络合物性能对比。测试结果表明:镍的络合物比钴的络合物具有更好的稳定性。
In order to investigate the effects of the central metal atoms on photothermal stability of dithiodiene complexes,in the paper, a near-infrared of dithiodiene cobalt complex containing a long carbon chain was designed and synthesized,and the photo-stability and thermal-stability of the two metal complexes were investigated.The results show that the nickel complex was more stable than the cobalt complex.
作者
刘蕊
王尚
高雪
张拓
张洪波
韩爱鸿
LIU Rui;WANG Shang;GAO Xue;ZHANG Tuo;ZHANG Hong-bo;HAN Ai-hong(College of Chemistry and Chemical Engineering,Shenyang Normal University,Shenyang 11034, Liaoning China;Experimental Teaching Center,Shenyang Normal University,Shenyang 11034,Liaoning China)
出处
《染料与染色》
CAS
2018年第6期1-4,共4页
Dyestuffs and Coloration
基金
辽宁省大学生创新与创业项目计划No:201710166044
关键词
长碳链
硫代双烯络合物
近红外染料
光热特性
long carbon chain
dithiolene metal complexes
near-infrared dye
photothermal properties
