摘要
2,6-萘二甲酸二甲酯和乙二醇酯交换反应为探针反应,研究了催化剂种类及其用量、乙二醇/2,6-萘二甲酸二甲酯摩尔比对探针反应动力学影响。实验结果表明,2,6-萘二甲酸二甲酯和乙二醇酯交换反应不是单纯地遵循二级反应动力学。催化剂种类、用量以及乙二醇/2,6-萘二甲酸二甲酯摩尔比均对探针反应动力学方程有影响。
Transesterification of NDC with EG is a kind of probe reaction. We study the effects of the catalyst and the molar ratio of EG to NDC on the dynamics of the probe reaction. The results show that the Transesterification does not simply follow the law of second-order reaction. The properties and quantity of the catalysts and the molar ratio of EG to NDC all influence the probe reaction dynamic formula.
出处
《长春工业大学学报》
CAS
2014年第3期246-250,共5页
Journal of Changchun University of Technology
基金
长春市科技计划项目(10GH24)
