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Enhanced hydrogen production from aqueous methanol solution using TiO2/Cu as photocatalysts

Enhanced hydrogen production from aqueous methanol solution using TiO2/Cu as photocatalysts
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摘要 The photocatalytic hydrogen production from aqueous methanol solution using titanium dioxide (TiO2) was investigated in the addition of metal particles including copper, lead, tin, and zinc. The results show that only the addition of copper particles enhances the hydrogen production. The copper usage and reaction temperature were further optimized for TiO2/Cu photocatalyts. Under the optimal conditions, the hydrogen production using TiO2/Cu as photocatalysts is approxi- mately 68 times higher than that obtained with only TiO2. The photocatalytic hydrogen production from aqueous methanol solution using titanium dioxide (TiO2) was investigated in the addition of metal particles including copper, lead, tin, and zinc. The results show that only the addition of copper particles enhances the hydrogen production. The copper usage and reaction temperature were further optimized for TiO2/Cu photocatalyts. Under the optimal conditions, the hydrogen production using TiO2/Cu as photocatalysts is approxi- mately 68 times higher than that obtained with only TiO2.
出处 《Frontiers of Chemical Science and Engineering》 SCIE EI CAS CSCD 2014年第2期197-202,共6页 化学科学与工程前沿(英文版)
关键词 photocatalytic hydrogen generation metha-nol copper particles TIO2 metal-semiconductor interface photocatalytic hydrogen generation, metha-nol, copper particles, TiO2, metal-semiconductor interface
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参考文献34

  • 1Yu J, Hai Y, Cheng B. Enhanced photocatalytic Hrproduction activity of TiO2 by Ni(OHh cluster modification. Journal of Physical Chemistry C, 2011,115(11): 4953-4958.
  • 2Cuberio M L, Fierro J L G. Partial oxidation of methanol over supported palladium catalysts. Applied Catalysis A, General, 1998, 168(2): 307-322.
  • 3Agrell J, Hasselbo K, Jansson K, Jaras S G, Boutonnet M. Production of hydrogen by partial oxidation of methanol over Cui ZnO catalysts prepared by microemulsion technique. Applied Catalysis A, General, 2001,211(2): 239-250.
  • 4de Wild P J, Verhaak M J F M. Catalytic production of hydrogen from methanol. Catalysis Today, 2000, 60(1-2): 3-10.
  • 5Shishdo T, Yamamoto Y, Morioka H, Takehira K. Production of hydrogen from methanol over Cu/ZnO and Cu/ZnO/ Al2O3 catalysts prepared by homogeneous precipitation: Steam reforming and oxidative steam reforming. Journal of Molecular Catalysis A Chemical, 2007, 268(1-2): 185-194.
  • 6Wu G S, Wang L C, Liu Y M, Cao Y, Dai W L, He H Y, Fan K N. Implication of the role of oxygen anions and oxygen vacancies for methanol decomposition over zirconia supported copper catalysts. Applied Surface Science, 2006, 253(2): 974-982.
  • 7Murcia-Mascardos S, Navarro R M, Gomez-Sainero L, Costantino U, Nocchetti M, Fierro J L G. Oxidative methanol reforming reactions on CuZnAI catalysts derived from hydrotalcite-like precursors. Journal of Catalysis, 2001, 198(2): 338-347.
  • 8Wu N L, Lee M S. Enhanced TiO2 photocatalysis by Cu in hydrogen production from aqueous methanol solution. International Journal of Hydrogen Energy, 2004, 29(15): 1601-1605.
  • 9Yang X, Salzmann C, Shi H, Wang H, Green M L H, Xiao T. The role of photoinduced defects in TiO2 and its effects on hydrogen evolution from aqueous methanol solution. Journal of Physical Chemistry A, 2008, 112(43): 10784-10789.
  • 10Lin W C, Yang W D, Huang I L, Wu T S, Chung Z 1. Hydrogen production from methanollwater photocatalytic decomposition using Pt/TiO2-xN catalyst. Energy & Fuels, 2009, 23(4): 2192- 2196.

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