摘要
Visible light irradiation combined with homogeneous iron and/or hydrogen peroxide to degrade organic dye rhodamine B (RhB) and small molecular compound 2,4-dichlorophenol (2,4-DCP) in a home-made bottle reactor was assessed. The concen-tration of oxidize species, Fe3+ and Fe2+ were determined during the degradation process. The results demonstrated that visible light irradiation combined with electro-Fenton improved the degradation efficiency. Moreover, both RhB and 2,4-DCP were mineralized during visible light synergistic electro-Fenton oxidation process. 95.0% TOC (total organic carbon) removal rate of RhB occurred after 90 min and 96.7% of COD (chemical oxygen demand) removal rate after 65 min of irradiation. 91.3% TOC removal rate of 2,4-DCP occurred after 16 h of irradiation and 99.9% COD removal rate occurred after 12 h of illumination. The degradation and oxidation process was dominated by the hydroxyl radical ( · OH) generated in the system. Both the impressed electricity and dye sensitization by visible light facilitated the conversion between Fe3+ and Fe 2+ , thus, improving Fenton reaction efficiency.
Visible light irradiation combined with homogeneous iron and/or hydrogen peroxide to degrade organic dye rhodamine B （RhB） and small molecular compound 2,4-dichlorophenol （2,4-DCP） in a home-made bottle reactor was assessed. The concen- tration of oxidize species, Fe3＋ and Fe2＋ were determined during the degradation process. The results demonstrated that visible light irradiation combined with electro-Fenton improved the degradation efficiency. Moreover, both RhB and 2,4-DCP were mineralized during visible light synergistic electro-Fenton oxidation process. 95.0% TOC （total organic carbon） removal rate of RhB occurred after 90 min and 96.7% of COD （chemical oxygen demand） removal rate after 65 min of irradiation. 91.3% TOC removal rate of 2,4-DCP occurred after 16 h of irradiation and 99.9% COD removal rate occurred after 12 h of illumina- tion. The degradation and oxidation process was dominated by the hydroxyl radical （＇OH） generated in the system. Both the impressed electricity and dye sensitization by visible light facilitated the conversion between Fe3＋ and Fe2＋, thus, improving Fenton reaction efficiency.
基金
supported by China National Funds for Distinguished Young Scientists (50925932)
the National Natural Science Foundation of China (21177072, 21207079)
Open Foundation about Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission& Ministry of Education of Hubei Province (CHCL10007)
