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Eu^(3+)和Bi^(3+)共掺杂锆酸钡荧光粉的制备及发光性质研究 被引量:10

Synthesis and Photoluminescence Properties of Eu^(3+),Bi^(3+) Codoped BaZrO_3 Phosphors
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摘要 在还原气氛下采用高温固相法制备了BaZrO3∶0.05Bi,xEu(x=0,0.010,0.025,0.050)荧光粉,并研究了其发光性能。研究证实:Bi,Eu共掺杂的BaZrO3荧光粉在近紫外340nm激发下,具有来自于Bi 3+的宽带发射峰和Eu3+的特征发射;Bi 3+对Eu3+具有能量传递和敏化作用,通过Bi 3+和Eu3+之间的能量传递获得了具有白色发光的BaZrO3荧光粉。 The BaZrO3∶0.05Bi,xEu(x=0,0.010,0.025,0.050) phosphors were prepared by using high-temperature solid-state reaction in reducing atmosphere,and their photoluminescence properties were investigated.The broadband emission peak of Bi3+ and the typical emission peaks of Eu3+ were observed in the BaZrO3 phosphors co-doped with Bi3+ and Eu3+ under 340 nm excitation.It is confirmed that energy transfer occurred between Bi3+ and Eu3+ in the BaZrO3∶Bi,Eu phosphors,and the white light BaZrO3 phosphors can be obtained through the energy transfer between Bi3+ and Eu3+.
出处 《光谱学与光谱分析》 SCIE EI CAS CSCD 北大核心 2013年第1期19-22,共4页 Spectroscopy and Spectral Analysis
基金 国家自然科学基金项目(51002068)资助
关键词 能量传递 铕离子 铋离子 锆酸钡 Energy transfer Bi ion Eu ion BaZrO3
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