摘要
The oil sorption capacity of composite materials made up of different polymeric fabrics (namely acrylic fabric (AF), polypropylene nonwoven (PP), and silk stocking (SS) as composite out-packing materials) and expanded perlite (EP) was evaluated for oil removal from the water. The effects of sorbent dosage, desorption time, oil amount in the water, and contact time on composite materials sorption were investigated. The results showed that the optimum quantity of EP was between 0.5 g and 1.0 g for 25 cm2 polymeric fabrics bags. Oil removal efficiency for 6 L/m2 of oil amount in the water was 52%-72%, 44%-63%, and 37%-48% for AF, PP, and SS composite materials, respectively. Oil/water selectivity analysis of different composite materials showed that AF composite material had a very high degree of hydrophobicity and oil sorption capacity of approximately 10.17 g/g. Both oil sorption kinetics and equilibrium studies were carried out, and the equilibrium process of composite materials was described well by the Langmuir isotherm, and the oil sorption kinetics of composite materials showed good correlation coefficients for the pseudo-second order kinetic model. Intra-particle diffusion studies showed that oil sorption mechanism was controlled by the three processes, involving in external liquid membrane diffusion, surface sorption, and intra-particle diffusion.
The oil sorption capacity of composite materials made up of different polymeric fabrics （namely acrylic fabric （AF）, polypropylene nonwoven （ PP ）, and silk stocking （SS） as composite out-packing materials） and expanded perlite （EP） was evaluated for oil removal from the water. The effects of sorbent dosage, desorption time, oil amount in the water, and contact time on composite materials sorption were investigated. The results showed that the optimum quantity of EP was between 0.5g and 1.0g for 25 cmz polymeric fabrics bags. Oil removal efficiency for 6 L/m2 of oil amount in the water was 52%-72%, 44%-63%, and 37%-48% for AF, PP, and SS composite materials, respectively. OiL/water selectivity analysis of different composite materials showed that AF composite material had a very high degree of hydrophobicity and oil sorption capacity of approximately 10. 17 g/g. Both oil sorption kinetics and equilibrium studies were carried out, and the equilibrium process of composite materials was described well by the Langmuir isotherm, and the oil sorptlon kinetics of composite materials showed good correlation coefficients for the pseudo-second order kinetic model. Intra-partiele diffusion studies showed that oil sorption mechanism was controlled by the three processes, involving in external liquid membrane diffusion, surface sorption, and intraparticle diffusion.
基金
National Important Science & Technology Specific Projects of China ( No. 2009ZX07317-006-02,No. 2009ZX07318-008-007)
State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology,China ( No. 2013DX06)
