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Study on the Recovery of Rhodium from Spent Organic Rhodium Catalysts of Acetic Acid Industry Using Pyrometallurgical Process 被引量:7

Study on the Recovery of Rhodium from Spent Organic Rhodium Catalysts of Acetic Acid Industry Using Pyrometallurgical Process
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摘要 A new process recycling rhodium from organic waste containing rhodium in acetic acid industry is developed. Use the special affinity of base metal sulfides (FeS, Ni2S3 , CuS, etc.) on platinum group metals, adopting high nickel matte trapping-aluminothermic activation method to recovery rhodium from incinerator residue of organic rhodium waste. The method is shorter process, lower equipment requirement, and the higher activity of rhodium black. In pyrometallurgy enrichment process,the recovery rate of rhodium reached 94.65%, the full flow of rhodium recovery rate was 92.04%. A new process recycling rhodium from organic waste containing rhodium in acetic acid industry is developed. Use the special affinity of base metal sulfides (FeS, Ni2S3, CuS, etc.) on platinum group metals, adopting high nickel matte trapping-aluminothermic activation method to recovery rhodium from incinerator residue of organic rhodium waste. The method is shorter process, lower equipment requirement, and the higher activity of rhodium black. In pyrometallurgy enrichment process, the recovery rate of rhodium reached 94.65%, the full flow of rhodium recovery rate was 92.04%.
出处 《贵金属》 CAS CSCD 北大核心 2012年第A01期24-27,共4页 Precious Metals
基金 the National High Technology Research and Development Program of China(863 Program): (2012AA063203, 2012AA063204, 2012AA063207)
关键词 METALLURGY organic waste platinum group metals RHODIUM refine pyrometallurgy enrichment metallurgy organic waste platinum group metals rhodium refine pyrometallurgy enrichment
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