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戊二醛改性壳聚糖的制备及其对酚类化合物的吸附性能 被引量:4

Preparation of N-alkyl chitosan and its adsorption of 2,4-dichlorophenol
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摘要 目的制备改性的壳聚糖(CTS),对其吸附氯酚的性能进行研究。方法通过戊二醛作为交联剂将壳聚糖进行改性,用红外光谱(FTIR)对改性后的壳聚糖进行了表征。考察了吸附时间、溶液pH值、氯酚浓度等因素对吸附的影响。结果改性CTS具有较好的抗酸碱性能;在pH6.5、吸附40min时对氯酚的吸附量最大;改性后的CTS吸附能力增加了13.8倍;且能再生和重复使用。结论经戊二醛交联后的壳聚糖是良好的氯酚吸附剂。 Objective To study the adsorption of 2,4-dichlorophenol of the modified chitosan.Methods A type of N-alkyl chitosan derivative was synthesized by using glutaraldehyde as a kind of crosslinker and characterized by FTIR.The effects of adsorption conditions,such as time,pH,the concentration of 2,4-dichlorophenol and the amount of the modified chitosan on the adsorption quantity of 2,4-dichlorophenol adsorpted were studied.Results The resistance on acid and alkaline of N-alkyl chitosan exhibited was good acid resistance.At pH 6.5,the adsorption of 2,4-dichlorophenol reached the maximum in 40 minutes.Adsorption capability of the modified chitosan was increased by 13.8-fold and it could be regenerated and reused.Conclusion The crosslinked chitosan had good adsorption capability for 2,4-dichlorophenol.
出处 《卫生研究》 CAS CSCD 北大核心 2011年第6期698-701,共4页 Journal of Hygiene Research
基金 安徽省高校省级自然科学基金重点项目(No.KJ2008A084)
关键词 壳聚糖 戊二醛 氯酚 吸附 chitosan glutaraldehyde 2 4-dichlorophenol adsorption
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  • 1MCCALL I C, BETANZOS A, WEBER D A, et al. Effects of phenol on barrier function of a human intestinal epithelial cell line correlate with altered tight junction protein localization [ J ]. Toxicol Appl Pharmacol,2009,241 ( 1 ) :61-70.
  • 2GHATBANDHE A S,YENKIE M K. 2,4 dichlorophenol (2,4-DCP) sorption from aqueous solution using granular activated carbon and polymeric adsorbents and studies on effect of temperature on activated carbon adsorption [ J ]. J Environ Sci Eng, 2008,50 (2) : 163-168.
  • 3YANG K, WU W, JING Q, et al. Competitive Adsorption of Naphthalene with 2, 4-Dichlorophenol and 4-Chloroaniline on Muhiwalled Carbon Nanotubes [ J ]. Environ Sci Technol, 2010,44 ( 8 ) : 3021-3027.
  • 4GONZALEZA.LEZ L F, SARRIA V, SA.NCHEZ O F. Degradation of chlorophenols by sequential biological-advanced oxidative process using Trametes pubescens and TiO ( 2 )/UV [ J ]. Bioresour Technol, 2010,101 (10) :3493-3499.
  • 5PEREZ-PANTOJA D, DE LA IGLESIA R, PIEPER D H, et al. Metabolic reconstruction of aromatic compounds degradation from the genome of the amazing pollutant-degrading bacterium Cupriavidus necator JMP134 [ J ]. FEMS Microbiol Rev,2008,32 (5) :736-794.
  • 6GONZALEZ P S, AGOSTINI E, MILRAD S R. Comparison of the removal of 2,4-dichlorophenol and phenol from polluted water, by peroxidases from tomato hairy roots, and protective effect of polyethylene glycol [ J ]. Chemosphere ,2008,70 ( 6 ) :982-989.
  • 7ZHAO L, MA J, ZHAI X. Synergetic effect of ultrasound with dual fields for the degradation of nitrobenzene in aqueous solution [ J ]. Environ Sci Techno1,2009,43 ( 13 ) :5094-5099.
  • 8陈天明,王世和,许琦,严金龙.壳聚糖及其衍生物的吸附性能及对含酚废水治理的应用[J].日用化学品科学,2006,29(7):22-24. 被引量:2
  • 9杨琥,袁博,卢耀柏,程镕时.壳聚糖磁性微球的制备及在水处理中的应用[J].中国科学(B辑),2008,38(9):755-761. 被引量:22
  • 10KRISHNAPRIYA K R, KANADASWAMY M. Synthesis and characterization of a crosslinked chitosan derivative with a complexing agent and its adsorption studies toward metal(Ⅱ) ions[J]. Carbohydr Res,2009,34g ( 13 ) : 1632-1638.

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