摘要
Structurally simple salicylaldehyde-based fluoreseent sensors for amino acids have been obtained by one-step or two-step synthesis.These sensors show significant fluorescence enhancement in the presence of many amino acids at concentrations as low as 10~5 mol/L.The reversible reaction of the aldehydes with amino acids to form imines in aqueous solution is proposed to account for the observed fluorescence enhancement.
Structurally simple salicylaldehyde-based fluoreseent sensors for amino acids have been obtained by one-step or two-step synthesis.These sensors show significant fluorescence enhancement in the presence of many amino acids at concentrations as low as 10~5 mol/L.The reversible reaction of the aldehydes with amino acids to form imines in aqueous solution is proposed to account for the observed fluorescence enhancement.
基金
the National Natural Science Foundation of China(No.20876090)
the Foundation for Research Initiation of Shaanxi University of Science&Technology(No.BJ09-15)
Foundation for Innovative Research Team of Shaanxi University of Science&Technology(No.TD09-04)for financial support