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非化学计量比镁铝尖晶石透明陶瓷的制备及性能 被引量:6

Preparation and Properties of Non-stoichiometric Magnesia-alumina Spinel Transparent Ceramics
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摘要 制备了一系列非化学计量比镁铝尖晶石粉体及透明陶瓷(MgO.nAl2O3,n=1,1.5,2,4),研究了n值对粉体物相的影响以及n值与陶瓷中波红外透过率、抗弯强度的关系。n值为1.5、2、4时,MgO.nAl2O3粉体仍可保持纯尖晶石相。MgO.1.5Al2O3透明陶瓷在具备与计量比镁铝尖晶石透明陶瓷(MgAl2O4,即MgO.Al2O3)相当的优良中波红外透过率的同时,抗弯强度从152 MPa提高至215 MPa,提高幅度达41%。力学性能的提升有利于镁铝尖晶石透明陶瓷的应用。 A series of non-stoichiometric magnesia-alumina spinel powder and transparent ceramics were prepared(MgO · nAl2O3, n = 1, 1.5, 2, 4). The effect of "n" on the powder phase, optical property and flexural strength of transparent ceramics were investigated in this paper. When n = 1.5, 2, 4, MgO · nAl2O3 powder are in pure spinel phase. The flexural strength of MgO · 1.5 Al2O3 is improved greatly from 152 MPa(MgO · Al2O3) to 215 MPa(MgO · 1.5 Al2O3) by a growth rate of 41%, Mid-IR transmittance of MgO · 1.5 Al2O3 and stoichiometrie magnesia-alumia spinel ( MgA1204, MgOoAl2O3 ) are matched also. The improvement of flexural strength is advantageous to the application of magnesia-alumia spinel transparent ceramics.
出处 《硅酸盐通报》 CAS CSCD 北大核心 2011年第4期891-894,共4页 Bulletin of the Chinese Ceramic Society
关键词 镁铝尖晶石 透明陶瓷 非化学计量比 中波红外 抗弯强度 magnesia-alumina spinel transparent ceramics non-stoichiometric mid-IR flexural strength
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