摘要
以炭黑表面大量存在的芳香族稠环化学物为基础，以缩合反应引进羟甲基，并利用羟甲基和铈离子之间的氧化还原引发反应探讨丙烯酸酯单体在炭黑表面的接枝聚合反应。
A redox system consisting of ceric ion and hydroxymethyl groups on carbon black was capable of initiating the radical polymerization of acrylate The introduction of hydroxymethyl groups on carbon black surface was achieved by reaction of formaldehyde with carbon black in the presence of basic catalysts The effects of the HEMA/AA ratio, the concentration of ceric ion and HNO 3, reaction time and the monomer content on the grafting efficiency were investigated The result of SEM showed that the hyperdispersed polyacrylate g carbon could disperse well in water
出处
《中山大学学报（自然科学版）》
CAS
CSCD
北大核心
1999年第4期40-43,共4页
Acta Scientiarum Naturalium Universitatis Sunyatseni
基金
广州市科委科技基金
关键词
超分散剂
接枝聚合
炭黑
丙烯酸酯
graft polymerization
carbon black
hyperdispersant
