摘要
A new three-dimensional supramolecular [Ce2（2,5-pydc）3（H2O）2]（1） has been hydrothermally synthesized at 180 ℃ and characterized by single-crystal X-ray diffraction.X-ray crystal analyses reveal that the compound belongs to the monoclinic system,space group P21/c,C21H13Ce2N3O14,a = 6.561（1）,b = 17.986（5）,c = 9.411（3） ,β = 95.558（5）° and Z = 2.In the structure of 1,each Ce（1） center is surrounded by 2,5-pydc ligands,forming the 6-connected node,and the 2,5-pydc ligand coordinates to the Ce（Ⅲ） in two different coordination modes.In mode 1,the four oxygen atoms of two carboxyl groups connect neighboring Ce（Ⅲ） ions,giving 4-connected（4-c） second building unit（SBU-1）.Furthermore,the structure is extended into a 2-D layer from SBU-1 by sharing Ce（1） atoms.In mode 2,the ligand coordinates to the Ce（Ⅲ） ion from the adjacent chain with the 4-connected（4-c） second building unit（SBU-2）,generating a 1-D ladder from SBU-2 by sharing Ce（1） atoms.Finally,the structure is extended into a 6,4,4-c network.Its photoluminescence property was also investigated.
A new three-dimensional supramolecular [Ce2（2,5-pydc）3（H2O）2]（1） has been hydrothermally synthesized at 180 ℃ and characterized by single-crystal X-ray diffraction.X-ray crystal analyses reveal that the compound belongs to the monoclinic system,space group P21/c,C21H13Ce2N3O14,a = 6.561（1）,b = 17.986（5）,c = 9.411（3） ,β = 95.558（5）° and Z = 2.In the structure of 1,each Ce（1） center is surrounded by 2,5-pydc ligands,forming the 6-connected node,and the 2,5-pydc ligand coordinates to the Ce（Ⅲ） in two different coordination modes.In mode 1,the four oxygen atoms of two carboxyl groups connect neighboring Ce（Ⅲ） ions,giving 4-connected（4-c） second building unit（SBU-1）.Furthermore,the structure is extended into a 2-D layer from SBU-1 by sharing Ce（1） atoms.In mode 2,the ligand coordinates to the Ce（Ⅲ） ion from the adjacent chain with the 4-connected（4-c） second building unit（SBU-2）,generating a 1-D ladder from SBU-2 by sharing Ce（1） atoms.Finally,the structure is extended into a 6,4,4-c network.Its photoluminescence property was also investigated.
