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Behavior of different phosphorus species in suspended particulate matter in the Changjiang estuary 被引量:14

Behavior of different phosphorus species in suspended particulate matter in the Changjiang estuary
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摘要 Suspended particulate matter (SPM) collected in the Changjiang (Yangtze River) estuary in June 2006 was separated into five fractions via water elutriation: clay-very fme silt (〈8 μm), fine silt (8-16 μm), medium silt (16--32 μm), coarse silt (32~53 μm) and sand (〉63 μm). The SPM and fractionated particles were sequentially analyzed by a modified SEDEX sequential extraction method to obtain six species of phosphorus: exchangeable or loosely-sorbed P, organic P, Fe-bound P, authigenic P, detrital P and refractory P. The results indicated that all particulate phosphorus species except for detrital P were negatively correlated to particle size; a high detrital P content was found in coarse silt and very coarse silt. From the inside of the river mouth to the gate of the fiver mouth, organic P, Fe-bound P and refractory P in the suspended particles decreased and a higher amount of exchangeable P appeared around the gate of the fiver mouth. From the gate of the river mouth to the sea, exchangeable P and organic P in suspended panicles increased distinctly. The total particulate P flux into the estuary from the Changjiang River was about 45.45×10^8μmol/s during sampling. Of this, about 8.27×10^8μmol/s was associated with the "truly suspended" fraction. The bio-available particulate P flux was about 13.58×10^8μmol/s. Of this, about 4.24 ×10^8μmol/s w as transported by "truly suspended" particles. Suspended particulate matter (SPM) collected in the Changjiang (Yangtze River) estuary in June 2006 was separated into five fractions via water elutriation:clay-very fine silt (<8 μm),fine silt (8-16 μm),medium silt (16-32 μm),coarse silt (32-63 μm) and sand (>63 μm).The SPM and fractionated particles were sequentially analyzed by a modified SEDEX sequential extraction method to obtain six species of phosphorus:exchangeable or loosely-sorbed P,organic P,Fe-bound P,authigenic P,detrital P and refractory P.The results indicated that all particulate phosphorus species except for detrital P were negatively correlated to particle size;a high detrital P content was found in coarse silt and very coarse silt.From the inside of the river mouth to the gate of the river mouth,organic P,Fe-bound P and refractory P in the suspended particles decreased and a higher amount of exchangeable P appeared around the gate of the river mouth.From the gate of the river mouth to the sea,exchangeable P and organic P in suspended particles increased distinctly.The total particulate P flux into the estuary from the Changjiang River was about 45.45×108 μmol/s during sampling.Of this,about 8.27×108 μmol/s was associated with the "truly suspended" fraction.The bio-available particulate P flux was about 13.58×108 μmol/s.Of this,about 4.24×108 μmol/s was transported by "truly suspended" particles.
出处 《Chinese Journal of Oceanology and Limnology》 SCIE CAS CSCD 2009年第4期859-868,共10页 中国海洋湖沼学报(英文版)
基金 Supported by the National Natural Science Foundation of China (Nos.40976044,40920164004 and 30490232) the National Basic Research Program of China (973 Program) (Nos.2002CB12405 and 2005CB422305)
关键词 Changjiang estuary particle size fractions particulate phosphorus species 悬浮微粒 有机磷 长江口 悬浮颗粒物 行为 连续提取方法 SEDEX 河口水
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