期刊文献+

载金属离子的介孔炭对噻吩吸附性能的研究 被引量:2

Thiophene Adsorption Properties by Mesoporous Carbon Supported Metallic Catalysts
在线阅读 下载PDF
导出
摘要 采用模板法制备了介孔炭,并利用浸渍法将金属离子N i2+、Co2+负载在该介孔材料上。研究了不同吸附剂、温度和浓度对吸附的影响。结果表明,介孔炭负载N i2+或Co2+比13X负载N i2+脱硫效果好,N i2+/介孔炭比Co2+/介孔炭脱硫效果好。当负载N i2+的量为10%,温度为20℃时,介孔炭的脱硫效果最好。 Mesoporous carbon was synthesized adopting template technique, and then metallic ions such as Ni^2+, Co^2+ were encapsulated into mesoporous materials utilizing impregnation technique. The influences of adsorption were studied by using different sorbent, under different temperatures and different concentrations. The results showed that the desulfurizing effects of Ni^2+/mesoporous carbon or Co^2+/ mesoporous carbon was better than Ni^2+/13X, and the desulfurizing effects of Ni^2+/mesoporous carbon was better than Co^2+/mesoporous carbon. The highest desulfurizing efficiency was obtained when the 10% of Ni^2+ was encapsulated on mesoporous carbon and the experiment temperature was 20℃.
出处 《山东化工》 CAS 2009年第11期16-18,共3页 Shandong Chemical Industry
关键词 介孔炭 噻吩 脱硫 吸附 mesoporous carbon thiophene desulfurization adsorption
  • 相关文献

参考文献8

二级参考文献50

  • 1李文,郭树才.煤的乙醇超临界萃取脱硫[J].燃料化学学报,1994,22(1):83-88. 被引量:6
  • 2钟蕴英 关梦嫔 等.煤化学[M].徐州:中国矿业大学出版社,1992.49-52.
  • 3解京选 匡亚莉.煤炭加工与综合利用[M].,1995(6).10.
  • 4[1]Marroquin-Sanchez G,Ancheyta-Juarez J.Catalytic hydrotreating of middle distillates blends in a fixed-bed pilot reactor[J].Applied Catalysis A:General,2001,207(1):407-420.
  • 5[2]Macaud M,Milenkovic A,Schulz E,et al.Hydrodesulfurization of alkyldibenzothiophenes:Evidence of highly unreactive aromatic sulfur compounds[J].Journal of Catalysis,2000,193(1),255-263.
  • 6[3]Laudau M V.Deep hydrotreating of middle distillates from crude and shale oils[J].Catalysis Today,1997,36(4):393-429.
  • 7[4]Girgis M J,Gates B C.Reactivities,reaction,networks,and kinetics in high-pressure catalytic hydroprocessing[J].Ind Eng Chem Res,1991,30(9):2021-2058.
  • 8[5]Gilman H,Jcoby A L.Dibenzothiophene:Orientation and derivatives[J].J Org Chem,1938,3:108-119.
  • 9[6]Kuchm-Caubere C,Adach-Becker S,Fort Y,et al.Expeditious and efficient syntheses of pure 4-methyl and 4,6-disubstituted dibenzothiophene[J].Tetrahedron,1996,52(27):9087-9092.
  • 10[7]Bataille F,Lemberton J L,Michaud P,et al.Alkyldibenzothiophene hydrodesulfurization-promoter effect,reactivity,and reaction mechanism[J].Journal of Catalysis,2000,191(1):409-422.

共引文献62

同被引文献16

引证文献2

二级引证文献6

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部