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Synthesis and Photocatalytic Activity of TiO_2/V_2O_5 Composite Catalyst Doped with Rare Earth Ions 被引量:6

Synthesis and Photocatalytic Activity of TiO_2/V_2O_5 Composite Catalyst Doped with Rare Earth Ions
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摘要 TiO2/V2O5 catalyst doped with rare earth ions was prepared by sol-gel method. Titanium tetrapropoxide and vanadium pentoxide were used as precursor of the composite catalyst and rare earth ions were used as dopant. The crystal phases, crystalline sizes, microstructure, absorption spectra of doped composite catalyst were studied by XRD, EDS, FT-IR and UV-Vis. Photoactivity of the prepared catalyst under ultraviolet irradiation were evaluated by degradation of methyl orange (MO) in aqueous solution. It is shown that the prepared catalyst is composed of anatase and futile. The rare earth ions are highly dispersed in composite catalyst. All the doped catalysts appear higher photocatalytic activity than TiO2/V2O5 catalyst and catalyst doped with Ce^4+ present the best activity to MO. TiO2/V2O5 catalyst doped with rare earth ions was prepared by sol-gel method. Titanium tetrapropoxide and vanadium pentoxide were used as precursor of the composite catalyst and rare earth ions were used as dopant. The crystal phases, crystalline sizes, microstructure, absorption spectra of doped composite catalyst were studied by XRD, EDS, FT-IR and UV-Vis. Photoactivity of the prepared catalyst under ultraviolet irradiation were evaluated by degradation of methyl orange (MO) in aqueous solution. It is shown that the prepared catalyst is composed of anatase and futile. The rare earth ions are highly dispersed in composite catalyst. All the doped catalysts appear higher photocatalytic activity than TiO2/V2O5 catalyst and catalyst doped with Ce^4+ present the best activity to MO.
出处 《Journal of Rare Earths》 SCIE EI CAS CSCD 2007年第2期173-178,共6页 稀土学报(英文版)
基金 Project supported by the National Natural Science Foundation of China (50571003)
关键词 PHOTOCATALYSIS titanium dioxide composite catalyst rare earth ion CERIUM photocatalysis titanium dioxide composite catalyst rare earth ion cerium
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