摘要
以葡萄糖为碳源,采用一种新的碳热还原法制备LiFePO4／C正极材料．采用TG-DTA、XRD、TEM等手段对前驱体及产物进行了表征,研究了碳热还原的反应历程,测试了样品的电化学性能．结果表明,该碳热还原法可以降低煅烧温度．600℃烧结24h的样品在0．05C下首次放电容量达156mAh·g-1,在0．1、0．2、0．5、1C下首次放电容量分别为146、135、130、121mAh·g-1．该样品在1C下经过30次循环,容量还保持为119mAh·g-1,衰减仅为1．65％．
LiFePO4/C composite cathode materials were synthesized by a novel carbothermal reduco tion（CTR） method using glucose as carbon resource. The precursors and the products were characterized by TG-DTA, XRD, TEM, and the reaction mechanism was investigated. The electrochemical performance of the samples was measured. The results show that the new method can reduce synthesis temperature, and the sample prepared at 600℃ for 24h can deliver a discharge capacity of 156mAh·g^-1 at 0.05C. The first discharge capacities of LiFePO4 at 0.1C, 0.2C, 1C are 146mAh·g^-1, 135mAh·g^-1, 130mAh·g^-1, 121mAh·g^-1, respectively. It retains discharge capacity of 119mAh·g^-1 at 1C after 30 cycles, with only 1.56% capacity decrease.
出处
《无机材料学报》
SCIE
EI
CAS
CSCD
北大核心
2007年第2期283-286,共4页
Journal of Inorganic Materials
基金
国家自然科学基金(20376086)
教育部博士点资助项目(20030533001)
