摘要
我国西北地区主要层间氧化带砂岩型铀矿床的贫矿石(U≤0.01%)中铀主要以分散形式,被砂岩填隙物中的粘土、褐铁矿等矿物,以及碎屑物和矿物的裂隙面等吸附,偶呈显微(μm级)、超显微状(〈1μm)沥青铀矿(其次为铀石)。随着矿石铀品位的增高,其中呈铀矿物形式的铀的比例逐渐增大,在特高品位(U〉1%)的矿石中,铀基本呈铀矿物(沥青铀矿,偶有铀石)形式产出。类质同象铀的份额极微,其可利用性缺乏实际意义。矿石中铀矿物主要赋存于矿化砂岩的填隙部位及碎屑物、矿物的孔隙或解理中,有时可交代碳屑、黄铁矿、绿泥石、黑云母等。由矿石中U^4+/U^5+含量比例推算原生铀矿物(沥青铀矿)的近似含氧系数变化范围为2.35~2.74,均值为2.49,与沉积、淋积铀矿床中的铀氧化物含氧系数相当,表明该类铀矿床生于常温条件下。极少数样品落入低温热水成因沥青铀矿的含氧系数范围(含氧系数低至2.35),表明个别地段可能出现低温热水铀成矿作用,推测可能受断裂构造热的影响。进而推测,特富矿石(U〉1%)可能是源自深部、沿断裂上升的含铀低温热水叠造作用的产物,板状矿体便是深、浅部流体混合的证据之一。
Existing state of uranium in ore from interlayer oxidation zone sandstone-hosted uranium deposits in Yili basin and Tuha basin, NW China, was studied in the present work. The bulk of uranium in low-grade ores (U≤0.01%) is adsorbed by fissure-filling fine minerals, such as clays, and by microfissure plane of debris. The adsorbed uranium in high grade ores (U 0. 5%-1.0%), however, occurs mostly in the form of uranium minerals, primary pitchblende and rarely coffinite. Primary uranium mineral occurs in fissure-filling space, in pore or cleavage of minerals replacing carbonaceous debris, pyrite, biotite and chlorite, etc. Only a little portion of uranium exists in the form of isomorphous replacement of heavy clastic minerals, such as zircon, monazite and apatite, etc.
出处
《铀矿地质》
CAS
CSCD
2006年第4期193-201,共9页
Uranium Geology
基金
国家自然科学基金(批准号:40573022)
教育部高等学校博士点专项科研基金(批准号:20020284036)
南京大学大型贵重仪器设备开放测试基金联合资助
关键词
层间氧化带
砂岩型铀矿床
铀赋存形式
铀矿物
吸附作用
interlayer oxidation zone
sandstone hosted uranium deposit
existing state of uranium
uranium mineral
adsorption