摘要
以电化学方法得到一系列的萘衍生物聚合膜．通过Ｘ－光电子能谱，反射红外光谱方法研究了聚（１－萘胺）的聚合形式．采用量子化学计算得到本文所研究的萘衍生物的电荷密度、分子总能量等电子结构参数．发现这些聚合膜的ｐＨ响应与其电子结构参数有一定的关系．
The polymer films of naphthalene, including naphthylamine, naphthalenol and aminonaphthalenol, were obtained by electrochemical polymerization method. The polymerization form of 1-naphthylamine was studied by the infrared spectroscopy, X-photoelectron spectrometry and verified by quantum chemical calculation.It has been found that the pH response characteristics of the polymer films related to the molecular parameters.
出处
《湖南大学学报（自然科学版）》
EI
CAS
CSCD
1996年第2期36-40,共5页
Journal of Hunan University:Natural Sciences
关键词
萘
衍生物
聚合膜
PH响应
naphthalene derivative
polymer film
pH response
