摘要
Reactions of bitter salt with taurine-3,5-dibromo-salicylaldehyde schiff base gave one new Complex [Mg(Br2TSSB)(Phen)(H2O)]·H2O (Br2TSSB=Taurine 3,5-dibromo-Salicylaldehyde Schiff Base, phen=o-phenanthro- line), which was characterized by elemental analysis, IR and X-ray diffraction. The chemical formula weight of the complex is 625.58. It′s crystal belongs to monoclinic system with space group P21/c. The cell parameters are: a=1.8142(3) nm, b=0.81475(14) nm, c=1.641 7(3) nm, β=90.571(4)°, and Z=4, V=2.426 4(7) nm3, Dc=1.712 g· cm-3, F(000)=1248, μ=3.496 mm-1. The complexes form a 3D net structure in which they are connected with hy- drogen bonds and #-# stacking. The Mg! formed a distorted coordination tetragonal pyramid. CCDC: 286194.
Reactions of bitter salt with taurine-3,5-dibromo-salicylaldehyde schiff base gave one new Complex [Mg（Br2TSSB）（Phen）（H2O）]·H2O （Br2TSSB=Taurine 3,5-dibromo-Salicylaldehyde Schiff Base, phen=o-phenanthroline）, which was characterized by elemental analysis, IR and X-ray diffraction. The chemical formula weight of the complex is 625.58. It＇s crystal belongs to monoclinic system with space group P21/c. The cell parameters are： a=1.8142（3） nm, b=0.81475（14） nm, c=1.641 7（3） nm,β=90.571（4）°, and Z=4, V=2.4264（7） nm^3 Dc=1.712 g·cm^-3, F（000）=1248,μ=3.496 mm^-1. The complexes form a 3D net structure in which they are connected with hydrogen bonds and π-π stacking. The Mg（Ⅱ） formed a distorted coordination tetragonal pyramid. CCDC： 286194.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2006年第1期179-182,共4页
Chinese Journal of Inorganic Chemistry
基金
广西自然科学基金项目(No.0339034)
广西教育厅科研项目(No.[2004]20)资助。
