摘要
The fracture behavior of disordered and ordered Ni4Mo alloy was investigated by tensile tests in hydrogen gas or during hydrogen charging. The results show that the ductility of the disordered alloy decreased slightly with the hydrogen pressure increasing, while that of the ordered alloy decreased rapidly with the hydrogen pressure increasing. However, the ductility of both disordered and ordered alloys reduced similarly seriously with the charging current density increasing. Therefore, the mechanism of order-induced embrittlement of Ni4 Mo alloy in hydrogen gas is supposed to be that atomic order accelerates the kinetics of the catalytic reaction for the dissociation of molecular H2 into atomic H.
The fracture behavior of disordered and ordered Ni4Mo alloy was investigated by tensile tests in hydrogen gas or during hydrogen charging. The results show that the ductility of the disordered alloy decreased slightly with the hydrogen pressure increasing, while that of the ordered alloy decreased rapidly with the hydrogen pressure increasing. However, the ductility of both disordered and ordered alloys reduced similarly seriously with the charging current density increasing. Therefore, the mechanism of order-induced embrittlement of Ni4 Mo alloy in hydrogen gas is supposed to be that atomic order accelerates the kinetics of the catalytic reaction for the dissociation of molecular H2 into atomic H.
基金
Project supported by National Natural Science Foundatron of China（ Grant No.59895157）, and Science Foundation of Shanghai Municipal Commission of Science and Technology （Grant No. 02ZE14033 ）
